Hydrothermal synthesis and crystal structure of two Co phosphonates containing trifunctional phosphonate anions:Co_3(O_3PCH_2NH_2CH_2PO_3)_2 and Co_3(O_3PCH_2-NC_4H_7-CO_2)_2 centre dot 5H_2O

Adele Turner; Paul-Alain Jaffres; Elizabeth J.MacLean; Didier Villemin; Vickie McKee; Gary B.Hix

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Hydrothermal synthesis and crystal structure of two Co phosphonates containing trifunctional phosphonate anions:Co_3(O_3PCH_2NH_2CH_2PO_3)_2 and Co_3(O_3PCH_2-NC_4H_7-CO_2)_2 centre dot 5H_2O

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Hydrothermal synthesis and crystal structure of two Co phosphonates containing trifunctional phosphonate anions:Co_3(O_3PCH_2NH_2CH_2PO_3)_2 and Co_3(O_3PCH_2-NC_4H_7-CO_2)_2 centre dot 5H_2O

机译：含有三官能膦酸酯阴离子的两个Co膦酸酯的水热合成和晶体结构：Co_3（O_3PCH_2NH_2CH_2PO_3）_2和Co_3（O_3PCH_2-NC_4H_7-CO_2）_2中心点5H_2O

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Two cobalt phosphonates containing trifunctional phosphonate anions have been synthesised and their structures solved by single crystal diffraction.Co_3(O_3PCH_2NH_2CH_2PO_3)_2(3)was formed as blue crystals.The material has three channel systems in the [001] direction formed by the cross-linking of chains of tetrahedrally co-ordinated Co atoms.Co_3(O_3PCH_2-NC_4H_7-CO_2)_2 centre dot 5H_2O(4),which contains anions derived from proline,was formed as purple crystals.(4)is composed of layers that contain holes.The layers stack in the [001] direction such that channels are formed in the same direction,in which the water molecules are located.

机译：合成了两种含三官能膦酸根阴离子的膦酸钴，并通过单晶衍射解决了它们的结构。Co_3（O_3PCH_2NH_2CH_2PO_3）_2（3）形成为蓝色晶体。该材料在[001]方向上具有三通道结构，由交叉结构形成。四面体配位的Co原子的链的连接。形成了紫色晶体的Co_3（O_3PCH_2-NC_4H_7-CO_2）_2中心点5H_2O（4）为紫色晶体。（4）由包含孔的层组成所述层沿[001]方向堆叠，使得沿与水分子所在方向相同的方向形成通道。

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《Dalton transactions: An international journal of inorganic chemistry》 |2003年第7期|共6页
作者
Adele Turner; Paul-Alain Jaffres; Elizabeth J.MacLean; Didier Villemin; Vickie McKee; Gary B.Hix;
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1. Hydrothermal synthesis and crystal structure of two Co phosphonates containing trifunctional phosphonate anions:Co_3(O_3PCH_2NH_2CH_2PO_3)_2 and Co_3(O_3PCH_2-NC_4H_7-CO_2)_2 centre dot 5H_2O [J] . Adele Turner, Paul-Alain Jaffres, Elizabeth J.MacLean, Dalton transactions: An international journal of inorganic chemistry . 2003,第7期

机译：含有三官能膦酸酯阴离子的两个Co膦酸酯的水热合成和晶体结构：Co_3（O_3PCH_2NH_2CH_2PO_3）_2和Co_3（O_3PCH_2-NC_4H_7-CO_2）_2中心点5H_2O
2. Microwave-assisted synthesis, crystal structures and thermal behaviour of Na_5Y(CO_3)_4 and Na_5Yb(CO_3)_4 centre dot 2H_2O [J] . M.O. Awaleh, A. Ben Ali, V. Maisonneuve Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics . 2003,第1a2期

机译：Na_5Y（CO_3）_4和Na_5Yb（CO_3）_4中心点2H_2O的微波辅助合成，晶体结构和热行为
3. Hydrothermal synthesis,crystal structure,thermal behaviour,IR and Raman spectroscopy of Na_3Y(CO_3)_3 centre dot 6 H_2O [J] . Amor Ben Ali, Mohamed Osman Awaleh, Marc Leblanc, Comptes Rendus Chimie . 2004,第6a7期

机译：Na_3Y（CO_3）_3中心点6 H_2O的水热合成，晶体结构，热行为，IR和拉曼光谱
4. Synthesis and Crystal Structure of the Flexible Ligand Coordination Polymer Co_3(bpd)_(5.5)(NCS)_6(NH_3)_n·2H_2O (bpd= 1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene) [C] . Yuqi Liu, Yong Yang, Rui Yang, International Conference on Chemical Engineering, Metallurgical Engineering and Metallic Materials . 2013

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5. Investigation of phosphonate biosynthesis: I. Structure of dehydrophos II. Mechanism of hydroxyethylphosphonate dioxygenase [D] . Whitteck, John Thomas 2010

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6. Synthesis of the Sulphonate and Phosphonate Derivatives ofMercaptoacetyltriglycine. X-Ray Crystal Structure of Na2ReO(Mercaptoacetylglycylglycylaminomethanesulphonate)·3H2O [O] . Lory Hansen, Andrew Taylor Jr., Luigi G. Marzilli 1994

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7. Hydrothermal synthesis and crystal structure of a new family of lanthanide phosphonates: H3N(CH2)4NH3LnhedpH2hedpH [O] . L. Roces, S. García-Granda, J. R. García, 2006

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8. Two Heteropoly Anions Containing Organic Groups. The Crystal and Molecular Structures of Ammonium Pentamolybdobis (methyl-phosphonate) Pentahydrate and Sodium Tetramethylammonium Pentamolybdobis (ethylammoniumphosphonate) Pentahydrate. [R] . stalick,judith k. quicksall,carl o. 1976

机译：两个含有机基团的杂多阴离子。五氧化二磷酸铵（甲基膦酸酯）五水合物和四甲基铵五氧化二磷酸铵（乙基铵膦酸酯）五水合物的晶体和分子结构。

Hydrothermal synthesis and crystal structure of two Co phosphonates containing trifunctional phosphonate anions:Co_3(O_3PCH_2NH_2CH_2PO_3)_2 and Co_3(O_3PCH_2-NC_4H_7-CO_2)_2 centre dot 5H_2O

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