Phosphine and arsine adducts of N-donor palladacycles as catalysts in the Suzuki coupling of aryl bromides

Robin B. Bedford; Catherine S. J. Cazin; Simon J. Coles; Thomas Gelbrich; Michael B. Hursthouse; Veronique J. M. Scordia

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Phosphine and arsine adducts of N-donor palladacycles as catalysts in the Suzuki coupling of aryl bromides

机译：N-供体palladacycles的膦和a加合物作为芳基溴化物的Suzuki偶联反应的催化剂

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Triarylphosphine and arsine adducts of imine- and amine-based palladacycles have been produced and the crystal structures of three examples have been determined, as has the structure of a parent imine-based palladacycle. The complexes were tested in the Suzuki coupling of an electronically deactivated aryl bromide and the phosphine adducts were found to show much greater activity than the parent palladacycles. Triarylphosphine adducts are preferable to trialkylphosphine adducts as they not only show higher activity but they are also more easily synthesised.

机译：已生产出基于亚胺和胺的palladacycles的三芳基膦和砷化氢加合物，并确定了三个实施例的晶体结构，以及基于亚胺的基于palladacycle的结构。在电子失活的芳基溴化物的Suzuki偶联中测试了该配合物，发现该膦加合物显示出比母体palladacycles更大的活性。三芳基膦加合物优于三烷基膦加合物，因为它们不仅显示出较高的活性，而且它们也更易于合成。

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《Dalton transactions: An international journal of inorganic chemistry》 |2003年第17期|共7页
作者
Robin B. Bedford; Catherine S. J. Cazin; Simon J. Coles; Thomas Gelbrich; Michael B. Hursthouse; Veronique J. M. Scordia;
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1. Phosphine and arsine adducts of N-donor palladacycles as catalysts in the Suzuki coupling of aryl bromides [J] . Robin B. Bedford, Catherine S. J. Cazin, Simon J. Coles, Dalton transactions: An international journal of inorganic chemistry . 2003,第17期

机译：N-供体palladacycles的膦和a加合物作为芳基溴化物的Suzuki偶联反应的催化剂
2. Di- and tri-alkylphosphine adducts of S-donor palladacycles as catalysts in the Suzuki coupling of aryl chlorides [J] . Bedford RB, Cazin CSJ, Hursthouse MB, Dalton transactions: An international journal of inorganic chemistry . 2004,第22期

机译：S-供体palladacycles的二烷基和三烷基膦加合物作为芳基氯的Suzuki偶联反应的催化剂
3. Graphene Oxide-Supported Oxime Palladacycles as Efficient Catalysts for the Suzuki–Miyaura Cross-Coupling Reaction of Aryl Bromides at Room Temperature under Aqueous Conditions [J] . Melania Gómez-Martínez, Alejandro Baeza, Diego A. Alonso Catalysts . 2017,第3期

机译：氧化石墨烯支持的肟Palladacycles在室温和水性条件下作为芳烃溴化物的Suzuki-Miyaura交叉偶联反应的有效催化剂
4. Ruthenocenyl Phosphine Designed as Novel Class of Phosphine-Arene Ligand: Application to Suzuki-Miyaura Reaction of Electronically and Sterically Deactivated Aryl Halides with Aryl Boronic Acids [C] . Takashi Hoshi, Taichi Nakazawa, Toshio Suzuki Symposium on Organometallic Chemistry . 2006

机译：设计为新型膦 - 芳烃配体的钌烯基膦：用芳族硼酸的电子和空间去激活的芳基卤化物的铃木 - 咪糕的反应应用
5. Part I. Asymmetric hydrosilylation of acetophenone using titanium catalysts. Part II. Synthesis of water-soluble palladacycles and their applications to the Suzuki reaction. Part III. Rhodium-catalyzed addition of aryl and alkenylboronic acids to aldehyde [D] . Huang, Rongcai. 2005

机译：第一部分：使用钛催化剂的苯乙酮不对称氢化硅烷化。第二部分水溶性palladacycles的合成及其在铃木反应中的应用。第三部分铑催化的芳基和烯基硼酸加成醛
6. t-Bu3P-Coordinated 2-Phenylaniline-Based Palladacycle Complex as a Precatalyst for the Suzuki Cross-coupling Polymerization of Aryl Dibromides with Aryldiboronic Acids [O] . Hong-Hai Zhang, Chun-Hui Xing, Georges Bouobda Tsemo, -1

机译：T-Bu3p-配位的基于2-苯基苯基钯络合物作为氨基硼酸芳基二溴化物的铃木交叉偶联聚合的预催化剂
7. Graphene Oxide-Supported Oxime Palladacycles as Efficient Catalysts for the Suzuki–Miyaura Cross-Coupling Reaction of Aryl Bromides at Room Temperature under Aqueous Conditions [O] . Gómez-Martínez, Melania, Baeza, Alejandro, Alonso, Diego A. 2017

机译：氧化石墨烯支持的肟Palladacycles作为芳烃在室温下水溶液中的Suzuki-Miyaura交叉偶联反应的有效催化剂

Phosphine and arsine adducts of N-donor palladacycles as catalysts in the Suzuki coupling of aryl bromides

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