Ammonia - borane: the hydrogen source par excellence?

Stephens FH; Pons V; Baker RT

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Ammonia - borane: the hydrogen source par excellence?

【24h】

Ammonia - borane: the hydrogen source par excellence?

机译：氨-硼烷：卓越的氢源？

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Ammonia-borane, H3NBH3, is an intriguing molecule for chemical hydrogen storage applications. With both protic N-H and hydridic B-H bonds, three H atoms per main group element, and a low molecular weight, H3NBH3 has the potential to meet the stringent gravimetric and volumetric hydrogen storage capacity targets needed for transportation applications. Furthermore, devising an energy-efficient chemical process to regenerate H3NBH3 from dehydrogenated BNHx material is an important step towards realization of a sustainable transportation fuel. In this perspective we discuss current progress in catalysis research to control the rate and extent of hydrogen release and preliminary efforts at regeneration of H3NBH3.

机译：氨硼烷H3NBH3是用于化学氢存储应用的有趣分子。具有质子化的N-H和氢键B-H，每个主族元素三个H原子，并且分子量低，H3NBH3有潜力满足运输应用所需的严格的重量和体积氢存储容量目标。此外，设计一种节能的化学工艺以从脱氢的BNHx材料中再生H3NBH3是实现可持续运输燃料的重要一步。从这个角度，我们讨论了控制氢释放速率和程度的催化研究的最新进展以及H3NBH3再生的初步工作。

著录项

来源
《Dalton transactions: An international journal of inorganic chemistry》 |2007年第25期|共14页
作者
Stephens FH; Pons V; Baker RT;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
ELECTRON-SPIN RESONANCE; CERAMIC CONVERSION REACTIONS; YIELD POLYMERIC PRECURSOR; METAL-ORGANIC FRAMEWORKS; INITIO DIRECT DYNAMICS; BORON-NITROGEN BONDS; LEWIS BASE ADDUCTS; N-H COMPOUNDS; THERMAL-DECOMPOSITION; CHEMICAL EVIDENCE;

机译：电子-自旋共振;陶瓷转化反应;屈服聚合物前体;金属有机骨架;INITIO直接动力学;硼氮键;路易斯碱添加剂;N-H化合物;热分解;化学分解;

相似文献

外文文献
中文文献
专利

1. Ammonia - borane: the hydrogen source par excellence? [J] . Stephens FH, Pons V, Baker RT Dalton transactions: An international journal of inorganic chemistry . 2007,第25期

机译：氨-硼烷：卓越的氢源？
2. Semihydrogenation of alkynes in the presence of Ni(0) catalyst using ammonia-borane and sodium borohydride as hydrogen sources [J] . Rigoberto Barrios-Francisco, Juventino J. Garcia Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications . 2010,第1a2期

机译：使用氨硼烷和硼氢化钠作为氢源，在Ni（0）催化剂存在下炔烃的半氢化反应
3. Graphene hydrogel supported palladium nanoparticles as an efficient and reusable heterogeneous catalysts in the transfer hydrogenation of nitroarenes using ammonia borane as a hydrogen source [J] . PariaEghbali, BilalNi?anc?, ?nderMetin Pure and Applied Chemistry . 2018,第2期

机译：石墨烯水凝胶负载钯纳米粒子，作为使用氨基硼烷作为氢气源的硝基甲烷的转移氢化的有效和可重复使用的非均相催化剂
4. Ammonia Borane Dehydrogenation Always Generates Ammonia, How Much and How to Remove It? [C] . Ahmad Al-Kukhun, Hyun Tae Hwang, Arvind Varma AIChE annual meeting . 2010

机译：氨硼烷脱氢总是产生氨，多少氨以及如何去除氨？
5. Catalytic Dehydrogenation of Ammonia Borane-Polyvinylpyrrolidone Hydrogen Storage Composites with Different Molecular Weights [D] . Seemaladinne, Ramanjaneyulu. 2017

机译：不同分子量氨硼烷-聚乙烯基吡咯烷酮储氢复合材料的催化脱氢
6. Probing the second dehydrogenation step in ammonia-borane dehydrocoupling: characterization and reactivity of the key intermediate B-(cyclotriborazanyl)amine-borane [O] . Hassan A. Kalviri, Felix Gärtner, Gang Ye, 2015

机译：探索氨-硼烷脱氢偶联反应中的第二个脱氢步骤：关键中间体B-（环三氮杂硼烷基）胺-硼烷的表征和反应性
7. Ruthenium nanoparticles confined in SBA-15 as highly efficient catalyst for hydrolytic dehydrogenation of ammonia borane and hydrazine borane [O] . Qilu Yao, Zhang-Hui Lu, Kangkang Yang, 2015

机译：钌纳米粒子局限于SBA-15，作为氨硼烷和肼硼烷的水解脱氢的高效催化剂
8. Chemical Hydrogen Storage Using Polyhedral Borane Anions and Aluminum-Ammonia-Borane Complexes. Final Report [R] . Hawthorne, M. F., Jalisatgi, S. S., Safronov, A. V., 2010

机译：使用多面体硼烷阴离子和铝 - 氨 - 硼烷配合物的化学氢储存。总结报告

Ammonia - borane: the hydrogen source par excellence?

摘要

著录项

相似文献

相关主题

期刊订阅