Photophysical and anion sensing properties of platinum(II)terpyridyl complexes with phenolic ethynyl ligands

Yang Fan; Yue-Mei Zhu; Feng-Rong Dai

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Photophysical and anion sensing properties of platinum(II)terpyridyl complexes with phenolic ethynyl ligands

机译：具有酚乙炔基配体的铂（II）吡啶基配合物的光物理和阴离子感测特性

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A series of platinum(II)terpyridyl complexes with phenolic ethynyl ligands have been synthesized and characterized.Their photophysical and sensing properties towards anions such as fluoride,acetate and dihydrogenphosphate have been investigated.These complexes show a colorimetric response and fluorescence quenching in the presence of anions including fluoride,acetate and dihydrogenphosphate,and selective sensing towards fluoride in some cases.The sensing mechanism has been investigated by spectrophotometric and ~1H NMR titration.

机译：合成并表征了一系列具有酚醛乙炔基配体的铂（II）对吡啶基配合物，研究了它们对氟，乙酸根和磷酸二氢根等阴离子的光物理和传感特性，这些配合物表现出比色反应和荧光猝灭。阴离子，包括氟离子，乙酸根和磷酸二氢根，在某些情况下对氟有选择性感测。已通过分光光度法和〜1H NMR滴定法研究了感测机理。

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《Dalton transactions: An international journal of inorganic chemistry》 |2007年第35期|共8页
作者
Yang Fan; Yue-Mei Zhu; Feng-Rong Dai;
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1. Photophysical and anion sensing properties of platinum(II)terpyridyl complexes with phenolic ethynyl ligands [J] . Yang Fan, Yue-Mei Zhu, Feng-Rong Dai Dalton transactions: An international journal of inorganic chemistry . 2007,第35期

机译：具有酚乙炔基配体的铂（II）吡啶基配合物的光物理和阴离子感测特性
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Photophysical and anion sensing properties of platinum(II)terpyridyl complexes with phenolic ethynyl ligands

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