Organically templated uranium(IV) fluorooxalates with layer structures: (H4TREN)[U2F6(C2O4)(3)]center dot 4H(2)O (TREN = tris(2-aminoethyl)amine) and (H(4)APPIP)[U2F6(C2O4)(3)]center dot 4H(2)O (APPIP=1,4-bis(3-aminopropyl)piperazine)

Wang CM; Wu YY; Chen PL; Lii KH

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Organically templated uranium(IV) fluorooxalates with layer structures: (H4TREN)[U2F6(C2O4)(3)]center dot 4H(2)O (TREN = tris(2-aminoethyl)amine) and (H(4)APPIP)[U2F6(C2O4)(3)]center dot 4H(2)O (APPIP=1,4-bis(3-aminopropyl)piperazine)

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Organically templated uranium(IV) fluorooxalates with layer structures: (H4TREN)[U2F6(C2O4)(3)]center dot 4H(2)O (TREN = tris(2-aminoethyl)amine) and (H(4)APPIP)[U2F6(C2O4)(3)]center dot 4H(2)O (APPIP=1,4-bis(3-aminopropyl)piperazine)

机译：具有层结构的有机模板氟草酸铀（IV）：（H4TREN）[U2F6（C2O4）（3）]中心点4H（2）O（TREN =三（2-氨基乙基）胺）和（H（4）APPIP）[ U2F6（C2O4）（3）]中心点4H（2）O（APPIP = 1,4-双（3-氨基丙基）哌嗪）

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Two organically-templated layered uranium(IV) fluorooxalates, (H4TREN)[U2F6(C2O4)(3)] center dot 4H(2)O ( 1) (TREN = tris(2-aminoethyl) amine) and (H(4)APPIP)[U2F6(C2O4)(3)] center dot 4H(2)O ( 2) (APPIP = 1,4-bis(3-aminopropyl) piperazine), have been synthesized by hydrothermal methods and structurally characterized by single-crystal X-ray diffraction, thermogravimetric analysis, and magnetic susceptibility. Both structures consist of anionic [U2F6(C2O4)(3)] 4- layers separated by organic ammonium cations and lattice water molecules. The UF3O6 polyhedra are connected by oxalate ligands in different ways within the layers. They are the first examples of organically-templated uranium fluorooxalates. Crystal data for compound 1 follow: monoclinic, P2(1)/c ( No. 14), a = 19.1563( 5) angstrom, b = 8.9531(2) angstrom, c = 16.6221( 4) angstrom, beta = 114.633(1)degrees, and Z = 4. Crystal data for compound 2 are the same as those for 1 except a = 10.3309(8) angstrom, b = 15.564(1) angstrom, c = 17.537(1) angstrom, and beta = 95.430(4)degrees.

机译：两个有机模板化的层状氟草酸铀（IV），（H4TREN）[U2F6（C2O4）（3）]中心点4H（2）O（1）（TREN =三（2-氨基乙基）胺）和（H（4） APPIP）[U2F6（C2O4）（3）]中心点4H（2）O（2）（APPIP = 1,4-双（3-氨基丙基）哌嗪），已通过水热法合成并通过单晶结构表征X射线衍射，热重分析和磁化率。两种结构均由被有机铵阳离子和晶格水分子分隔的阴离子[U2F6（C2O4）（3）] 4层组成。 UF3O6多面体在层中通过草酸酯配体以不同方式连接。它们是有机模板化的氟草酸铀的第一个实例。化合物1的晶体数据如下：单斜晶系，P2（1）/ c（第14号），a = 19.1563（5）埃，b = 8.9531（2）埃，c = 16.6221（4）埃，beta = 114.633（1 ，度数，Z =4。化合物2的晶体数据与a的晶体数据相同，除了a = 10.3309（8）埃，b = 15.564（1）埃，c = 17.537（1）埃和beta = 95.430（ 4）度。

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《Dalton transactions: An international journal of inorganic chemistry》 |2007年第10期|共4页
作者
Wang CM; Wu YY; Chen PL; Lii KH;
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正文语种 eng
中图分类无机化学;
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HYDROTHERMAL SYNTHESES; MAGNETIC-PROPERTIES; VARIABLE DIMENSIONALITY; FLUORIDES; SYSTEM; (C4N2H12)U2O4F6; OXYFLUORIDES; AQUOFLUORIDE; ZERO;

机译：水热合成;磁性能;变维;氟化物;体系;（C4N2H12）U2O4F6;羟基氟化物;氟化铝;零;

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1. Organically templated uranium(IV) fluorooxalates with layer structures: (H4TREN)[U2F6(C2O4)(3)]center dot 4H(2)O (TREN = tris(2-aminoethyl)amine) and (H(4)APPIP)[U2F6(C2O4)(3)]center dot 4H(2)O (APPIP=1,4-bis(3-aminopropyl)piperazine) [J] . Wang CM, Wu YY, Chen PL, Dalton transactions: An international journal of inorganic chemistry . 2007,第10期

机译：具有层结构的有机模板氟草酸铀（IV）：（H4TREN）[U2F6（C2O4）（3）]中心点4H（2）O（TREN =三（2-氨基乙基）胺）和（H（4）APPIP）[ U2F6（C2O4）（3）]中心点4H（2）O（APPIP = 1,4-双（3-氨基丙基）哌嗪）
2. Synthesis and structural characterization of (H(4)APPIP)[V-3(C2O4)(2) (HPO4)(3)(PO4)(H2O)center dot 6H(2)O(APPIP=1,4-bis(3-aminopropyl)piperazine), a layered vanadium oxalatophosphate containing double 6-ring units [J] . Tang MF, Lii KH International Journal of Quantum Chemistry . 2004,第6期

机译：（H（4）APPIP）[V-3（C2O4）（2）（HPO4）（3）（PO4）（H2O）中心点6H（2）O（APPIP = 1,4-bis（ 3-氨基丙基）哌嗪），含有双6环单元的层状草酸钒磷酸盐
3. Novel transition metal oxalatophosphates with a two-dimensional honeycomb structure: (H3TREN)[M-2(HPO4)(C2O4)(2.5)]center dot 3H(2)O (M = Mn-II and Fe-II, TREN = tris(2-aminoethyl)amine) [J] . Jiang YC., Wang SL., Lee SF., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2003,第20期

机译：具有二维蜂窝结构的新型过渡金属草酰磷酸盐：（H3TREN）[M-2（HPO4）（C2O4）（2.5）]中心点3H（2）O（M = Mn-II和Fe-II，TREN = tris （2-氨基乙基）胺）

Organically templated uranium(IV) fluorooxalates with layer structures: (H4TREN)[U2F6(C2O4)(3)]center dot 4H(2)O (TREN = tris(2-aminoethyl)amine) and (H(4)APPIP)[U2F6(C2O4)(3)]center dot 4H(2)O (APPIP=1,4-bis(3-aminopropyl)piperazine)

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