Well-defined polynuclear heterobimetallic complexes as precursors for ceramic and magnetic materials

Szafert S; John L; Sobota P

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Well-defined polynuclear heterobimetallic complexes as precursors for ceramic and magnetic materials

机译：定义明确的多核异双金属配合物，作为陶瓷和磁性材料的前体

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Well-defined heterobi- and heteropolymetallic alkoxides are valuable precursors for numerous oxide materials with great application potential. Simple and high yield synthetic routes to such compounds are always highly desirable. This Perspective describes one of the methods that utilizes, as starting materials, homoleptic monometallic alkoxides with a free alcoholic moiety coordinated to the metal. The moiety constitutes a convenient anchor for upcoming organometallics.

机译：定义明确的杂双金属和杂多金属醇盐是许多具有巨大应用潜力的氧化物材料的宝贵前体。一直非常需要简单且高产率的合成此类化合物的途径。该观点描述了一种方法，该方法利用具有与金属配位的游离醇部分的均一的单金属醇盐作为原料。该部分构成了即将到来的有机金属的便利锚。

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《Dalton transactions: An international journal of inorganic chemistry》 |2008年第46期|共12页
作者
Szafert S; John L; Sobota P;
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正文语种 eng
中图分类无机化学;
关键词
ALKALINE-EARTH METALS; RAY CRYSTAL-STRUCTURES; MOLECULAR-STRUCTURE; HETEROMETALLIC ALKOXIDES; STRUCTURAL-CHARACTERIZATION; BARIUM; MAGNESIUM; LIGANDS; REACTIVITY; STRONTIUM;

机译：碱土金属;射线晶体结构;分子结构;异规烷烃;结构表征;钡;镁;配体;反应性;锶;

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1. Well-defined polynuclear heterobimetallic complexes as precursors for ceramic and magnetic materials [J] . Szafert S, John L, Sobota P Dalton transactions: An international journal of inorganic chemistry . 2008,第46期

机译：定义明确的多核异双金属配合物，作为陶瓷和磁性材料的前体
2. Synthesis, spectroscopic investigations, X-ray crystallographic studies and magnetic properties of heterobimetallic Fe(II)-Hg(II) polynuclear complexes [J] . Jin L. T., Liu X. T., Wang X. Q., Materials Research Innovations . 2014,第1期

机译：异双金属Fe（II）-Hg（II）多核配合物的合成，光谱研究，X射线晶体学研究和磁性
3. Heterobimetallic Mn(II)-Hg(II) polynuclear complexes containing Hg(SCN)_4~(2-) unit - Synthesis, spectroscopic investigations, X-ray studies and magnetic properties [J] . MacHura B., Palion J., ?witlicka A., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2011,第15期

机译：含Hg（SCN）_4〜（2-）单元的异双金属Mn（II）-Hg（II）多核配合物-合成，光谱研究，X射线研究和磁性能
4. Heterobimetallic Complexes As Controlled Precursors for Atomically Dispersed, Promoted Methane Oxidation Catalysts [C] . Joseph Maalouf, Jay Schwalbe, Joshua J. Willis AIChE Annual Meeting . 2016

机译：异质金属复合物作为原子分散的受控前体，促进甲烷氧化催化剂
5. Modeling & processing of ceramic and polymer precursor ceramic matrix composite materials. [D] . Wang, Xiaolin. 2007

机译：陶瓷和聚合物前驱体陶瓷基复合材料的建模与加工。
6. Dinuclear Copper(II) Complexes with Schiff Bases Derived from 2-Hydroxy-5-Methylisophthalaldehyde and Histamine or 2-(2-Aminoethyl)pyridine and Their Application as Magnetic and Fluorescent Materials in Thin Film Deposition [O] . Magdalena Barwiolek, Anna Kaczmarek-Kędziera, Tadeusz M. Muziol, 2020

机译：具有2-羟基5-甲基间苯二甲醛和组胺或2-（2-氨基乙基）吡啶的席夫碱的双核铜（II）配合物及其在薄膜沉积中的磁性和荧光材料应用
7. Single-Molecule Magnets and Multifunctional Molecular Magnetic Materials Based on Polynuclear Metal Complexes [O] . Alexandropoulos Dimitrios 2016

机译：基于多核金属配合物的单分子磁体和多功能分子磁性材料
8. Synthesis of Heterobimetallic Complexes from Carbonyl Complexes of Bis(diisopropylamino)Phosphine [R] . King, R. B., Fu, W. K., Holt, E. M. 1985

机译：双（二异丙基氨基）膦羰基配合物合成异双金属配合物

Well-defined polynuclear heterobimetallic complexes as precursors for ceramic and magnetic materials

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