Designing new ligands: asymmetric cyclopropanation by Cu(I) complexes based on functionalised pyridine-containing macrocyclic ligands

Caselli A; Cesana F; Gallo E; Casati N; Macchi P; Sisti M; Celentano G; Cenini S

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Designing new ligands: asymmetric cyclopropanation by Cu(I) complexes based on functionalised pyridine-containing macrocyclic ligands

机译：设计新的配体：基于功能化的含吡啶大环配体的Cu（I）配合物的不对称环丙烷化

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摘要

The synthesis and characterisation of copper(I) complexes, including two crystal structures of the new chiral pyridine-containing macrocyclic ligands (PC-type), and their use as catalysts in asymmetric cyclopropanation reactions are reported.

机译：铜（I）配合物的合成和表征，包括新的手性含吡啶大环配体（PC型）的两个晶体结构，及其在不对称环丙烷化反应中用作催化剂的报道。

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《Dalton transactions: An international journal of inorganic chemistry》 |2008年第32期|共4页
作者
Caselli A; Cesana F; Gallo E; Casati N; Macchi P; Sisti M; Celentano G; Cenini S;
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正文语种 eng
中图分类无机化学;
关键词
COPPER-CATALYZED CYCLOPROPANATION;

机译：铜催化环丙烷;

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专利

1. Designing new ligands: asymmetric cyclopropanation by Cu(I) complexes based on functionalised pyridine-containing macrocyclic ligands [J] . Caselli A, Cesana F, Gallo E, Dalton transactions: An international journal of inorganic chemistry . 2008,第32期

机译：设计新的配体：基于功能化的含吡啶大环配体的Cu（I）配合物的不对称环丙烷化
2. Designing Novel Contrast Agents for Magnetic Resonance Imaging. Synthesis and Relaxometric Characterization of three Gadolinium (III) Complexes Based on Functionalized Pyridine-Containing Macrocyclic Ligands [J] . Silvio Aime, Eliana Gianolio, Davide Corpillo, Helvetica chimica acta . 2003,第3期

机译：设计用于磁共振成像的新型造影剂。基于功能化吡啶基大环配体的三种three（III）配合物的合成和弛豫表征
3. Reactions at the azomethine C=N bonds in the nickel (II) and copper (II) complexes of pyridine-containing Schiff-base macrocyclic ligands [J] . Aida M.Herrera, Ganna V.Kalayda, Jeremy S.Disch, Dalton transactions: An international journal of inorganic chemistry . 2003,第23期

机译：含吡啶的席夫碱大环配体的镍（II）和铜（II）配合物中的偶氮甲碱C = N键处的反应
4. DFT Study of Adiabatic Singlet-Triplet Energy Gaps in Ni(II)-based Macrocyclic-ligand Supramolecular Complexes [C] . Alex-Adrian Farcas, Attila Bende International Conference of Processes in Isotopes and Molecules . 2020

机译：Ni（II）中绝热单态三重态能量间隙的DFT研究 - 基于大环 - 配体超分子复合物
5. MANGANESE(II) AND COBALT(III) COMPLEXES OF MULTIDENTATE LIGANDS: I. MANGANESE(II) COMPLEXES OF A MACROCYCLIC PENTADENTATE LIGAND. II. COBALT(III) COMPLEXES OF LINEAR TETRAMINE LIGANDS. [D] . HAMILTON, HOBART GORDON, JR. 1968

机译：多齿配体的锰（II）和钴（III）配合物：I.大环戊二烯配体的锰（II）配合物。二。线性叔丁胺配体的钴（III）配合物。
6. Synthesis and characterization of the copper(II) complexes of new N2S2-donor macrocyclic ligands: synthesis and in vivo evaluation of the 64Cu complexes [O] . Grazia Papini, Simone Alidori, Jason S. Lewis, -1

机译：新的N2S2-供体大环配体的铜（II）配合物的合成和表征：64Cu配合物的合成和体内评估
7. Asymmetric cyclopropanation of olefins catalysed by Cu(I) complexes of chiral pyridine-containing macrocyclic ligands (Pc-L*) [O] . Castano, Brunilde, Guidone, Stefano, Gallo, Emma, 2013

机译：含手性吡啶的大环配体（Pc-L *）的Cu（I）配合物催化的烯烃的不对称环丙烷化

Designing new ligands: asymmetric cyclopropanation by Cu(I) complexes based on functionalised pyridine-containing macrocyclic ligands

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