Two enantiomers of [Cu-3(mnt)(3)](3-) as ligands to Cu(I) or Ag(I) in building [Cu6M2(mnt)(6)](4-) complexes (M = Cu or Ag) with the reversal of the reaction by X- (X = Cl, Br)

Maiti BK; Pal K; Sarkar S

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Two enantiomers of [Cu-3(mnt)(3)](3-) as ligands to Cu(I) or Ag(I) in building [Cu6M2(mnt)(6)](4-) complexes (M = Cu or Ag) with the reversal of the reaction by X- (X = Cl, Br)

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Two enantiomers of [Cu-3(mnt)(3)](3-) as ligands to Cu(I) or Ag(I) in building [Cu6M2(mnt)(6)](4-) complexes (M = Cu or Ag) with the reversal of the reaction by X- (X = Cl, Br)

机译：[Cu-3（mnt）（3）]（3-）的两个对映体，作为[Cu6M2（mnt）（6）]（4-）配合物中Cu（I）或Ag（I）的配体（M = Cu或银），反应逆转X-（X = Cl，Br）

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Two enantiomers of [Bu4N](3)[Cu-3(mnt)(3)] (1) formed by Na-2(mnt) (mnt = maleonitriledithiolate, [S2C2(CN)(2)](2-)) and CuCl in a 1:1 molar ratio react further with MCl (M = Cu or Ag) involving both the enantiomers of 1 to produce the larger complex, [Bu4N](4)[Cu6M2(mnt)(6)] (M= Cu (2), Ag (3)) from which the capped Cu+ or Ag+ ion can readily be removed by Bu4NX (X = Cl, Br), reverting 2 or 3 back to 1. Such reversal does not work with non-coordinating anions like BF4-, ClO4- and PF6-.

机译：Na-2（mnt）形成的[Bu4N]（3）[Cu-3（mnt）（3）]（1）的两个对映异构体（mnt =马来亚三硫代磺酸盐，[S2C2（CN）（2）]（2-））和摩尔比为1：1的CuCl与涉及1的两个对映异构体的MCl（M = Cu或Ag）进一步反应生成更大的络合物[Bu4N]（4）[Cu6M2（mnt）（6）]（M =可以通过Bu4NX（X = Cl，Br）轻松除去封端的Cu +或Ag +离子的Cu（2），Ag（3），将2或3还原为1。这种逆转不适用于非配位阴离子像BF4-，ClO4-和PF6-。

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《Dalton transactions: An international journal of inorganic chemistry》 |2008年第8期|共6页
作者
Maiti BK; Pal K; Sarkar S;
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正文语种 eng
中图分类化学;
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CHEMIE DES SCHWEFELKOHLENSTOFFS; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURE; CLUSTERS; ANIONS;

机译：碳的化学;分子结构;晶体结构;团簇;阴离子;

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1. Two enantiomers of [Cu-3(mnt)(3)](3-) as ligands to Cu(I) or Ag(I) in building [Cu6M2(mnt)(6)](4-) complexes (M = Cu or Ag) with the reversal of the reaction by X- (X = Cl, Br) [J] . Maiti BK, Pal K, Sarkar S Dalton transactions: An international journal of inorganic chemistry . 2008,第8期

机译：[Cu-3（mnt）（3）]（3-）的两个对映体，作为[Cu6M2（mnt）（6）]（4-）配合物中Cu（I）或Ag（I）的配体（M = Cu或银），反应逆转X-（X = Cl，Br）
2. Single-crystal EPR and theoretical investigations on the 'paramagnetic impurity' (n-B4N)(2)[Cu(mnt)(2)] built upon preparation of the antiferromagnetically coupled binuclear (n-Bu4N)(2)[(mnt)Cu(tto)Cu(mnt)] [J] . Teschmit G., Barthel A., Reinhold J., Inorganica Chimica Acta . 2000,第1期

机译：单晶EPR和基于反铁磁耦合双核（n-Bu4N）（2）[（mnt）的制备”的“顺磁性杂质”（n-B4N）（2）[Cu（mnt）（2）]的理论研究Cu（tto）Cu（mnt）]
3. Copper (Ⅰ) 1,1-dithiolate cluster transformations . Synthesis of [Bu_4N]_6(S, i-MNT)_6], i-MNT=S_2CC(CN)_2]~-, from [Bu_4N]_4[Cu_8(i-MNT)_6] with sulfur. Reaction of the cyclic hexanuclear complex with phosphine to give the tetrahedral [Bu_4N]_4[Cu_ [J] . C.W. Liu, Richard J. Staples, John P. Fackler Coordination Chemistry Reviews . 1998,第期

机译：1,1-二硫代铜（Ⅰ）簇转变。由[Bu_4N] _4 [Cu_8（i-MNT）_6]与硫合成[Bu_4N] _6（S，i-MNT）_6]，i-MNT = S_2CC（CN）_2]〜-。环状六核配合物与膦反应生成四面体[Bu_4N] _4 [Cu_
4. Size effect on the interfacial reactions and microstructural evolution of Cu/Sn3.0Ag0.5Cu-ball/Sn3.0Ag0.5Cu-paste/Cu joints in flip-chip on BGA packaging [C] . Jia-Qiang Huang, Min-Bo Zhou, Wang-Yun Li, International Conference on Electronic Packaging Technology . 2016

机译：尺寸对BGA封装倒装芯片中Cu / Sn3.0Ag0.5Cu球/Sn3.0Ag0.5Cu膏/ Cu接头的界面反应和微观结构演变的影响
5. Equilibrium charge state distributions of fast F, Si, Cl, Cu and Br ions after passage through thin foils [D] . Ishihara Toyoyuki 1984

机译：快速F，Si，Cl，Cu和Br离子穿过薄箔后的平衡电荷态分布
6. Glutathione-Mediated Cu(I)/Cu(II) Complexes: Valence-Dependent Effects on Clearance and In Vivo Imaging Application [O] . Su-Na Yin, Yuanyuan Liu, Chen Zhou, 2017

机译：谷胱甘肽介导的Cu（I）/ Cu（II）配合物：价依赖效应的清除和体内成像应用。
7. Heterospin Systems Constructed from Cu2Ln3+ and Ni(mnt)21-,2- Tectons: First 3p-3d-4f Complexes (mnt = maleonitriledithiolato) [O] . Madalan Augustin M, Avarvari Narcis, Fourmigué Marc, 2008

机译：由Cu2Ln 3+和Ni（mnt）2 1-，2-构造子构筑的杂杂旋体系：首批3p-3d-4f配合物（mnt =马来腈三硫代噻吩基）
8. Cluster Complex Metathesis. Synthesis, Structures, and Dynamic Behaviour of Bi- and Tri-Metallic Hexanuclear Cluster Complexes (MM'Ru4(millimicron3-H)2(CO)12(PPh3)2) (M ==M' == CU, Ag, or Au;M == CU, M' == Ag or Au; M == Ag, M' == [R] . Freeman, M. J., Green, M., Orphen, A. G., 1983

机译：簇复杂复分解。双金属和三金属六核簇合物（mm'Ru4（millimicron3-H）2（CO）12（pph3）2）（m == m'== CU，ag或au）的合成，结构和动态行为; m == CU，m'== ag或au; m == ag，m'==

Two enantiomers of [Cu-3(mnt)(3)](3-) as ligands to Cu(I) or Ag(I) in building [Cu6M2(mnt)(6)](4-) complexes (M = Cu or Ag) with the reversal of the reaction by X- (X = Cl, Br)

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