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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >A novel organotin-substituted polyoxomolybdate cluster
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A novel organotin-substituted polyoxomolybdate cluster

机译:新型有机锡取代的聚氧钼酸盐簇

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摘要

A novel organotin-substituted polyoxomolybdate cluster (H3O)(16)[(H2O)(2)(MoO)-O-V(OH)](2){(Mo28Mo4II)-Mo-VI(NO)(4)(BuSnO)(2)-[BuSn(OH)(2)](2)O-102(H2O)(12)}center dot 18H(2)O 1 was synthesized in a 'one-pot' reaction by adopting the reduction-oxidation-reconstitution self-assembly process, which shows a {Mo-34(NO)(4)Sn-4} mixed metal skeleton, which is constructed from two {Mo-16(NO)(2)Sn-2} subunits being linked by two MoO6 octahedra.
机译:新型有机锡取代的聚氧钼酸盐簇(H3O)(16)[(H2O)(2)(MoO)-OV(OH)](2){(Mo28Mo4II)-Mo-VI(NO)(4)(BuSnO)( 2)-[BuSn(OH)(2)](2)O-102(H2O)(12)}中心点18H(2)O 1通过“还原-氧化-重构自组装过程,显示了{Mo-34(NO)(4)Sn-4}混合金属骨架,该骨架由两个{Mo-16(NO)(2)Sn-2}子单元连接而成两个MoO6八面体。

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