...
首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >O-2 activation and hydrolysis of Salan rare-earth metal alkyl complexes
【24h】

O-2 activation and hydrolysis of Salan rare-earth metal alkyl complexes

机译:O-2活化和水解Salan稀土金属烷基络合物

获取原文
获取原文并翻译 | 示例
           

摘要

Salan ligated yttrium alkyl complex 1, (LY)-Y-1(CH2SiMe3)(THF) (Salan = L-1: [2-O-3,5-tBu(2)-C6H2CH2N(CH3) CH2](2)), was exposed to an oxygen/ nitrogen atmosphere to give a bimetallic alkoxide complex 4, [(LY)-Y-1(mu-OCH2SiMe3)](2). Whilst the lutetium counterparts 2 ((LLu)-Lu-1(CH2SiMe3)(THF)) and 3 ((LLu)-Lu-2(CH2SiMe3)(THF); L-2: [2-O-3-tBu-C6H2CH2N(CH3) CH2](2)) were hydrolysed with moist nitrogen to afford mixed hydroxy/silyloxy complexes 5 and 6 ([(LLu)-Lu-1,2(mu-OSiMe3)(mu-OH) LuL1,2]), respectively.
机译:Salan连接的钇烷基络合物1,(LY)-Y-1(CH2SiMe3)(THF)(Salan = L-1:[2-O-3,5-tBu(2)-C6H2CH2N(CH3)CH2](2) ),将其暴露在氧气/氮气气氛中,得到双金属醇盐络合物4,[(LY)-Y-1(mu-OCH2SiMe3)](2)。 the对应物2((LLu)-Lu-1(CH2SiMe3)(THF))和3((LLu)-Lu-2(CH2SiMe3)(THF); L-2:[2-O-3-tBu-将C6H2CH2N(CH3)CH2](2))用潮湿的氮气水解,得到混合的羟基/甲硅烷氧基络合物5和6([[(LLu)-Lu-1,2(mu-OSiMe3)(mu-OH)LuL1,2] ), 分别。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号