Isolation and characterization of stable, distinctly bent, trans-chelated bisphosphine palladium(0) species

Schnetz T; Roder M; Rominger F; Hofmann P

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Isolation and characterization of stable, distinctly bent, trans-chelated bisphosphine palladium(0) species

机译：稳定且明显弯曲的反螯合双膦钯（0）物种的分离和表征

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The novel ligands 3 and 4 (i-Pr-Rucaphos, Cy-Rucaphos) react with (tmeda) PdMe2 yielding ethane and distinctly bent, trans-spanning bisphosphine chelated 14-electron palladium(0) species, which have been fully characterized, including single crystal X-ray diffraction.

机译：新型配体3和4（i-Pr-Rucaphos，Cy-Rucaphos）与（tmeda）PdMe2反应生成乙烷并产生明显弯曲的，跨跨双膦螯合的14电子钯（0）物种，已充分表征，包括单晶X射线衍射。

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《Dalton transactions: An international journal of inorganic chemistry》 |2008年第17期|共3页
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Schnetz T; Roder M; Rominger F; Hofmann P;
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正文语种 eng
中图分类化学;
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APPROXIMATE COULOMB POTENTIALS; AUXILIARY BASIS-SETS; ELECTRONIC-STRUCTURE; METAL COMPLEXES; LIGANDS; COORDINATION; REACTIVITY; ATOMS;

机译：库仑近似电位;辅助基组;电子结构;金属配合物;配体;配位;反应性;原子;

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机译：稳定且明显弯曲的反螯合双膦钯（0）物种的分离和表征
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Isolation and characterization of stable, distinctly bent, trans-chelated bisphosphine palladium(0) species

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