Polymeric di- and discrete trinuclear silver(I) assemblies incorporating gamma-carbon bonded, neutral acetylacetone-imine motifs assembled from racemic and diastereopure N,N '-bis(acetylacetone)cyclohexanediimine units

Zhu BX; Zhang QL; Zhang YQ; Tao Z; Clegg JK; Reimers JR; Lindoy LF; Wei G

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Polymeric di- and discrete trinuclear silver(I) assemblies incorporating gamma-carbon bonded, neutral acetylacetone-imine motifs assembled from racemic and diastereopure N,N '-bis(acetylacetone)cyclohexanediimine units

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Polymeric di- and discrete trinuclear silver(I) assemblies incorporating gamma-carbon bonded, neutral acetylacetone-imine motifs assembled from racemic and diastereopure N,N '-bis(acetylacetone)cyclohexanediimine units

机译：聚合的双核和离散三核银（I）组件，由外消旋和非对映纯N，N'-双（乙酰丙酮）环己烷二亚胺单元组装而成，结合了γ-碳键合的中性乙酰丙酮-亚胺基序

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摘要

Diastereopure (1R,2R)-N,N'-bis(acetylacetone)cyclohexanedi-imine L-1 and its corresponding (1R,2R)L-1/(1S,2S)L-2 enantiomeric mixture react with AgNO3 to yield the unusual coordination polymer [Ag-2(L-1)(L-2)(NO3)(2)](n) (1) and the unique trimetallic discrete species {[Ag-3(L-1)(3)(mu(3)-O,O,O-NO3)(H2O)(3)](2)(NO3)}(NO3)(3)center dot 8.5H(2)O (2) which incorporates a symmetrical mu(3)-bridging nitrato group that gives rise to a C-3-symmetric triskelion motif; both species also feature gamma-carbon eta(1) aryl-like coordination of neutral bridging acetylacetone-imine units to the respective Ag(I) centres.

机译：非对映体（1R，2R）-N，N'-双（乙酰丙酮）环己烷二亚胺L-1及其对应的（1R，2R）L-1 /（1S，2S）L-2对映体混合物与AgNO3反应生成不寻常的配位聚合物[Ag-2（L-1）（L-2）（NO3）（2）]（n）（1）和独特的三金属离散物种{[Ag-3（L-1）（3）（ mu（3）-O，O，O-NO3）（H2O）（3）]（2）（NO3）}（NO3）（3）中心点8.5H（2）O（2），其中包含对称的mu（ 3）桥接硝基基团，产生一个C-3-对称的三方骨架基序;这两个物种还具有将中性架桥乙酰丙酮-亚胺单元连接到各自的Ag（I）中心的γ-碳eta（1）芳基样配合物。

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来源
《Dalton transactions: An international journal of inorganic chemistry》 |2009年第25期|共5页
作者
Zhu BX; Zhang QL; Zhang YQ; Tao Z; Clegg JK; Reimers JR; Lindoy LF; Wei G;
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正文语种 eng
中图分类化学;
关键词
Diastereopure; cyclohexanedi; polymer;

机译：非对映体;环己二;聚合物;

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1. Polymeric di- and discrete trinuclear silver(I) assemblies incorporating gamma-carbon bonded, neutral acetylacetone-imine motifs assembled from racemic and diastereopure N,N '-bis(acetylacetone)cyclohexanediimine units [J] . Zhu BX, Zhang QL, Zhang YQ, Dalton transactions: An international journal of inorganic chemistry . 2009,第25期

机译：聚合的双核和离散三核银（I）组件，由外消旋和非对映纯N，N'-双（乙酰丙酮）环己烷二亚胺单元组装而成，结合了γ-碳键合的中性乙酰丙酮-亚胺基序
2. Silver(I) coordination polymers incorporating neutral γ-carbon bound N, N ′-bis(acetylacetone)alkanediimine units [J] . Zhang Q.-L., Zhu B.-X., Zhang Y.-Q., Crystal growth & design . 2011,第12期

机译：结合中性γ-碳键合的N，N'-双（乙酰丙酮）烷二胺单元的银（I）配位聚合物
3. Silver(I) coordination polymers incorporating neutral γ-carbon bound N, N ′-bis(acetylacetone)alkanediimine units [J] . Zhang Q.-L., Zhu B.-X., Zhang Y.-Q., Crystal growth & design . 2011,第12期

机译：结合中性γ-碳键合的N，N'-双（乙酰丙酮）烷二胺单元的银（I）配位聚合物
4. Polymeric di- and discrete trinuclear silver(I) assemblies incorporating gamma-carbon bonded, neutral acetylacetone-imine motifs assembled from racemic and diastereopure N,N u27-bis(acetylacetone)cyclohexanediimine units [O] . Zhu Bi-Xue, Zhang Qi-Long, Zhang Yun-Qian, 2009

机译：聚合的双核和离散三核银（I）组件，结合了由外消旋和非对映纯N，N u27-双（乙酰丙酮）环己烷二亚胺单元组装而成的γ-碳键合的中性乙酰丙酮-亚胺基序

Polymeric di- and discrete trinuclear silver(I) assemblies incorporating gamma-carbon bonded, neutral acetylacetone-imine motifs assembled from racemic and diastereopure N,N '-bis(acetylacetone)cyclohexanediimine units

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