Design of organometallic group IV heteroallylic complexes and their catalytic properties for polymerizations and olefin centered transformations

Smolensky E; Eisen MS

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Design of organometallic group IV heteroallylic complexes and their catalytic properties for polymerizations and olefin centered transformations

机译：IV族有机金属杂烯丙基配合物的设计及其催化聚合和烯烃中心转化的性能

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The use of metallocenes in many stoichiometric and catalytic processes has been the impetus for the development of new organometallic complexes, especially those containing early transition metals. The formation of coordinative unsaturated complexes using allylic, benzamidinate and aminopyridine families is presented. The synthesis and structural parameters of the new complexes, their activation and use in the polymerization of alpha-olefins and dienes, in the dehydrogenative coupling of silanes and in the hydroamination reactions comprise the objectives of this review.

机译：在许多化学计量和催化过程中使用茂金属一直是开发新的有机金属配合物的动力，特别是那些含有早期过渡金属的配合物。介绍了使用烯丙基，苯甲酰胺酸酯和氨基吡啶家族形成配位不饱和配合物。新配合物的合成和结构参数，它们的活化作用和在α-烯烃和二烯聚合中的应用，在硅烷的脱氢偶联中以及在加氢胺化反应中的应用均构成了本综述的目标。

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《Dalton transactions: An international journal of inorganic chemistry》 |2007年第48期|共28页
作者
Smolensky E; Eisen MS;
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正文语种 eng
中图分类无机化学;
关键词
INTERMOLECULAR HYDROAMINATION REACTIONS; ANTI-MARKOVNIKOV HYDROAMINATION; ALKYL COORDINATION CATALYSTS; NUCLEAR MAGNETIC-RESONANCE; RAY CRYSTAL-STRUCTURE; LATE-METAL-CATALYSTS; INTRAMOLECULAR HYDROAMINATION; BENZAMIDINATE COMPLEXES; ZIRCONIUM COMPLEXES; METALLOCENE CATALYSTS;

机译：分子间加氢反应;反马尔可夫尼科夫加氢反应;烷基配位催化剂;核磁共振;射线晶体结构;金属催化;分子内加氢;复合物;直链状;

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1. Design of organometallic group IV heteroallylic complexes and their catalytic properties for polymerizations and olefin centered transformations [J] . Smolensky E, Eisen MS Dalton transactions: An international journal of inorganic chemistry . 2007,第48期

机译：IV族有机金属杂烯丙基配合物的设计及其催化聚合和烯烃中心转化的性能
2. Design of Postmetallocene Catalytic Systems of Arylimine Type for Olefin Polymerization: XVI.* Synthesis of (N-Aryl)salicylaldimines Containing Pent-4-enyloxy Group and Their Complexes with Titanium(IV) Dichloride [J] . I.I. Oleinik, I. V. Oleinik, D. E. Zaitsev Russian Journal of Organic Chemistry . 2014,第2期

机译：Arylimine型烯烃聚合后茂金属催化体系的设计：XVI。*含有Pent-4-烯氧基的（N-芳基）水杨醛亚胺及其与二氯化钛（IV）的配合物的合成
3. Design of postmetallocene catalytic systems of arylimine type for olefin polymerization: XVII. Synthesis of methoxy-substituted (p-aryl)salicylaldimines containing omega-alkenyloxy group, and their complexes with titanium(IV) dichloride [J] . Oleinik I. I., Oleinik I. V., Ivanchev S. S., Russian Journal of Organic Chemistry . 2014,第11期

机译：芳烃类型的茂金属后茂金属催化体系的设计：XVII。含ω-烯基氧基的甲氧基取代的（对芳基）水杨醛亚胺的合成及其与二氯化钛（IV）的配合物
4. Effect of co-catalyst on the polymerization of α-olefin monomers by (cyclopentadienyl) (nitroxide)titanium(IV) complexes [C] . Andrew P. Dove, Mahesh K. Mahanthappa, Robert M.Waymouth Division of Polymeric Material: Science and Engineering American Chemical Society meeting . 2004

机译：副催化剂对（环戊二烯基）（氮氧化锡）钛（IV）络合物聚合α-烯烃单体聚合的影响
5. Organometallic Reaction Mechanisms: Olefin Polymerization Catalysis and Carbon-Hydrogen Bond Activation by Early Transition Metal Bisphenolate Complexes and Protonolysis of Bipyrimidine Platinum Methyl Complexes. [D] . Golisz, Suzanne R. 2010

机译：有机金属反应机理：早期过渡金属双酚盐配合物的烯烃聚合催化和碳氢键活化以及联嘧啶铂甲基配合物的质子分解。
6. Rhodium and Iridium Mediated C-H and O-H Bond Activation of Two Schiff Base Ligands: Synthesis Characterization and Catalytic Properties of the Organometallic Complexes [O] . Poulami Sengupta, Rituparna Das, Papu Dhibar, 2021

机译：铑和铱介导的C-H和O-H键活化两种席夫碱配体：有机金属配合物的合成表征和催化性能
7. Chain-Walking Polymerization of α-Olefins by α-Diimine Ni(II) Complexes: Effect of Reducing the Steric Hindrance of Ortho- and Para-Aryl Substituents on the Catalytic Behavior, Monomer Enchainment, and Polymer Properties [O] . Ivana Pierro, Giorgia Zanchin, Emilio Parisini, 2018

机译：α-二亚胺Ni（II）配合物的α-烯烃的链行步行聚合：减少邻芳基取代基的催化行为，单体萃取物和聚合物性能的效果

Design of organometallic group IV heteroallylic complexes and their catalytic properties for polymerizations and olefin centered transformations

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