INDOLPhos: novel hybrid phosphine-phosphoramidite ligands for asymmetric hydrogenation and hydroformylation

Wassenaar J; Reek JNH

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INDOLPhos: novel hybrid phosphine-phosphoramidite ligands for asymmetric hydrogenation and hydroformylation

机译：INDOLPhos：用于不对称氢化和加氢甲酰化的新型杂化膦-亚磷酰胺配体

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摘要

Hybrid bidentate phosphine-phosphoramidite ligands are prepared in a modular 2-step sequence and their rhodium complexes display high selectivity in rhodium catalysed hydrogenation and hydroformylation reactions.

机译：混合式二齿膦-亚磷酰胺配体以模块化的两步顺序制备，它们的铑配合物在铑催化的加氢和加氢甲酰化反应中显示出高选择性。

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《Dalton transactions: An international journal of inorganic chemistry》 |2007年第34期|共4页
作者
Wassenaar J; Reek JNH;
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正文语种 eng
中图分类无机化学;
关键词
BIDENTATE LIGANDS; CATALYZED HYDROGENATION; HOMOGENEOUS CATALYSIS; COMPLEXES; PALLADIUM; ENANTIOSELECTIVITY; COORDINATION; QUINAPHOS; STYRENE; MODEL;

机译：双齿配体;催化加氢;均相催化;络合物;钯;对映选择性;配位;喹啉;苯乙烯;模型;

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1. INDOLPhos: novel hybrid phosphine-phosphoramidite ligands for asymmetric hydrogenation and hydroformylation [J] . Wassenaar J, Reek JNH Dalton transactions: An international journal of inorganic chemistry . 2007,第34期

机译：INDOLPhos：用于不对称氢化和加氢甲酰化的新型杂化膦-亚磷酰胺配体
2. Rhodium-catalyzed asymmetric hydroformylation with taddol-based indolphos ligands [J] . Wassenaar J., De Bruin B., Reek J.N.H. Organometallics . 2010,第12期

机译：t族基于吲哚磷配体的铑催化不对称羰基化反应
3. Synthesis and Application of Modular Phosphine-Phosphoramidite Ligands in Asymmetric Hydroformylation: Structure-Selectivity Relationship [J] . Zhang XW, Cao BN, Yan YJ, Chemistry: A European journal . 2010,第3期

机译：非对称羰基化反应中模块化膦-亚磷酰胺配体的合成与应用：结构-选择性关系
4. FLUORINATED POLYMERIC BINAP LIGAND FOR ASYMMETRIC HYDROGENATION IN SC CO_2 [C] . H. Altinel, G. Avsar, M. K. Yilmaz, European Meeting on Supercritical Fluids . 2008

机译：SC CO_2中不对称氢化的氟化聚合物BINAP配体
5. Rational catalyst design: Characterizing hydrogen activation in asymmetric hydrogenation and the chelate effect in hydroformylation. [D] . Brauch, Thomas Wayne. 1997

机译：合理的催化剂设计：表征不对称氢化中的氢活化和加氢甲酰化中的螯合作用。
6. Asymmetric Catalysis Special Feature Part II: Remarkably diastereoselective synthesis of a chiral biphenyl diphosphine ligand and its application in asymmetric hydrogenation [O] . Liqin Qiu, Jing Wu, Shusun Chan, 2004

机译：不对称催化特征第二部分：手性联苯二膦配体的非对映选择性合成及其在不对称氢化中的应用
7. Unsymmetrical Hybrid Ferrocene-Based Phosphine-Phosphoramidites: A New Class of Practical Ligands for Rh-Catalyzed Asymmetric Hydrogenation [O] . -1

机译：基于非对称的杂化二氧化烯磷酰磷酰胺：一种用于RH催化不对称氢化的新型实用配体

INDOLPhos: novel hybrid phosphine-phosphoramidite ligands for asymmetric hydrogenation and hydroformylation

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