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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >The first 1D twofold interpenetrating metal-organic network generated by 1D triple helical chains with nanosized cages
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The first 1D twofold interpenetrating metal-organic network generated by 1D triple helical chains with nanosized cages

机译:由具有纳米级笼的一维三重螺旋链生成的第一个一维双向互穿金属有机网络

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摘要

Reaction of AgPF6 with the asymmetric ligand 1,6-dihydro-2-methyl-6-oxo-(3,4'-bipyridine)5-carbonitrile (1), afforded a significant silver coordination polymer {[Ag-2(l)(3)](2)center dot(CH3OH)(3)center dot(PF6)(4)}(n) (2) with unique 1D twofold interpenetrating metal-organic frameworks constructed by 1D triple helical chains with nanosized cages hosting counterions as guests. This compound exhibits high thermal stability and blue-shift emission with large intensity enhancement compared with that of the free ligand.
机译:AgPF6与不对称配体1,6-二氢-2-甲基-6-氧代-(3,4'-联吡啶)5-腈(1)反应,制得显着的银配位聚合物{[Ag-2(l) (3)](2)中心点(CH3OH)(3)中心点(PF6)(4)}(n)(2)具有由一维三重螺旋链和具有抗衡离子的纳米级笼子构成的独特一维双向互穿金属有机骨架作为客人。与游离配体相比,该化合物显示出高的热稳定性和蓝移发射,强度增强了很多。

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