Characterization and alkane oxidation activity of a diastereopure seven-coordinate iron(III)alkylperoxo complex

Silvia Gosiewska; Hjalmar P.Permentier; Andries P.Bruins

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Characterization and alkane oxidation activity of a diastereopure seven-coordinate iron(III)alkylperoxo complex

机译：非对映体七配位铁（III）烷基过氧配合物的表征和烷烃氧化活性

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Spectroscopic characterization and alkane oxidation studies of a diastereopure seven-coordinate high-spin iron(III)alkylperoxo complex based on the chiral N,N',N-bis(L-prolinate)pyridine ligand Py(ProMe)2(1)are reported.In recent years,iron(ra)-peroxo species have been observed as intermediates in many biological oxidations catalyzed by mononuclear,non-heme iron enzymes and in the antitumor drug bleomycine.

机译：报道了基于手性N，N'，N-双（L-脯氨酸）吡啶配体Py（ProMe）2（1）的非对映纯七配位高自旋铁（III）烷基过氧配合物的光谱表征和烷烃氧化研究近年来，已观察到铁（ra）-过氧物质是单核非血红素铁酶催化的许多生物氧化反应的中间体，以及抗肿瘤药博来霉素的中间体。

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《Dalton transactions: An international journal of inorganic chemistry》 |2007年第31期|共4页
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Silvia Gosiewska; Hjalmar P.Permentier; Andries P.Bruins;
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1. Characterization and alkane oxidation activity of a diastereopure seven-coordinate iron(III)alkylperoxo complex [J] . Silvia Gosiewska, Hjalmar P.Permentier, Andries P.Bruins Dalton transactions: An international journal of inorganic chemistry . 2007,第31期

机译：非对映体七配位铁（III）烷基过氧配合物的表征和烷烃氧化活性
2. Chemistry and reactivity of dinuclear iron oxamate complexes: alkane oxidation with hydrogen peroxide catalysed by an oxo-bridged diiron(III) complex with amide and carboxylate ligation [J] . Pardo E, Lloret F, Carrasco R, Inorganica Chimica Acta . 2004,第9期

机译：双核草酸铁配合物的化学和反应活性：氧桥联二铁（III）配合物与酰胺和羧酸酯的连接催化过氧化氢的烷烃氧化
3. Synthesis and characterization of novel alkylperoxo mononuclear iron(III) complexes with a tripodal pyridylamine ligand: A model for peroxo intermediates in reactions catalyzed by non-heme iron enzymes [J] . Wada A., Watanabe Y., Mukai M., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1999,第16期

机译：具有三脚架吡啶胺配体的新型烷基过氧单核铁（III）配合物的合成和表征：非血红素铁酶催化反应中过氧中间体的模型
4. MONO- AND BINUCLEAR IRON COMPLEXES IN ZEOLITES AND MESOPOROUS OXIDES AS BIOMIMETIC ALKANE OXIDATION CATALYSTS [C] . NATO advanced study institute on catalytic activation and functionalisation of light alkanes . 1998

机译：沸石中的单核铁络合物和中孔氧化物作为仿生烷烃氧化催化剂
5. The structure and reactivity of a series of high-valent oxo complexes of Ru and Mn: Ru(III)-mediated catalytic oxygenation of triphenylphosphine, characterization of binuclear Mn(III,III) and Mn(III,IV) dimers, and mononuclear iron(III) and iron(IV). [D] . Fackler, Nathanael L. P. 1997

机译：Ru和Mn的一系列高价羰基配合物的结构和反应性：Ru（III）介导的三苯膦催化氧化，双核Mn（III，III）和Mn（III，IV）二聚体的表征以及单核铁（III）和铁（IV）。
6. Synthesis X-Ray Crystallographic Characterization and Electronic Structure Studies of a Di-Azide Iron(III) Complex: Implications for the Azide Adducts of Iron(III) Superoxide Dismutase [O] . Laurie E. Grove, Jason K. Hallman, Joseph P. Emerson, -1

机译：二叠氮化铁（III）配合物的合成X射线晶体学表征和电子结构研究：对铁（III）超氧化物歧化酶的叠氮加合物的影响
7. Characterization and alkane oxidation activity of a diastereopure seven-coordinate iron(III) alkylperoxo complex [O] . Gosiewska, Silvia, Permentier, Hjalmar P., Bruins, Andries P., 2007

机译：非对映体七配位铁（III）烷基过氧配合物的表征和烷烃氧化活性

Characterization and alkane oxidation activity of a diastereopure seven-coordinate iron(III)alkylperoxo complex

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