Remarkably stable dinuclear, diamagnetic rhenium(VI) salts with the [ReOCl4OReOCl4](2-) anion

Holynska M; Lis T

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Remarkably stable dinuclear, diamagnetic rhenium(VI) salts with the [ReOCl4OReOCl4](2-) anion

机译：具有[ReOCl4OReOCl4]（2-）阴离子的非常稳定的双核抗磁rh（VI）盐

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A reaction leading reproducibly to the stable salts containing mu-oxido-bis{cis-tetrachloridooxidorhenate(VI)} anion (systematic name: mu-oxido-bis{(OC-6-32)-tetrachloridooxidorhenate(VI)} anion) was described. A series of phosphonium salts was prepared in crystalline form and a detailed investigation of the complex anion structure was performed. The magnetic and spectroscopic properties are discussed on the example of the methyltriphenylphoshonium salt.

机译：描述了一种可重复地导致生成稳定的盐的反应，该稳定盐包含mu-oxido-bis {（cis-tetrachloridooxidorhenate（VI）}）阴离子（系统名称：mu-oxido-bis {（OC-6-32）-tetrachloridooxidorhenate（VI）}阴离子）。制备了一系列结晶形式的phospho盐，并对复合阴离子结构进行了详细研究。在甲基三苯基磷are盐的实例上讨论了磁性和光谱性质。

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《Dalton transactions: An international journal of inorganic chemistry》 |2009年第19期|共7页
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Holynska M; Lis T;
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正文语种 eng
中图分类化学;
关键词
MAIN GROUP ELEMENTS; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURES; TRANSITION-METALS; MULTIPLE BONDS; OXIDES; COMPLEXES;

机译：主要族元素;分子结构;晶体结构;过渡金属;多键;氧化物;络合物;

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1. Remarkably stable dinuclear, diamagnetic rhenium(VI) salts with the [ReOCl4OReOCl4](2-) anion [J] . Holynska M, Lis T Dalton transactions: An international journal of inorganic chemistry . 2009,第19期

机译：具有[ReOCl4OReOCl4]（2-）阴离子的非常稳定的双核抗磁rh（VI）盐
2. Structures, magnetic properties, and reactivity studies of salts containing the dinuclear anion [M2Cl6](2-) (M = Mn, Fe, Co) [J] . Sun JS., Xiang OY., Clerac R., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1999,第25期

机译：含双核阴离子[M2Cl6]（2-）（M = Mn，Fe，Co）的盐的结构，磁性和反应性研究
3. Diamagnetic pi-dimers of the [1,2,5]thiadiazolo[3,4-c][1,2,5]thiadiazolidyl radical anion in the crystalline state: Preparation and X-ray crystal structure of a [(Me2N)(2)CC(NMe2)(2)](2+)[(C2N4S2)(2)](2-) salt [J] . Gritsan NP, Lonchakov AV, Lork E, European journal of inorganic chemistry . 2008,第12期

机译：[1,2,5] thiadiazolo [3,4-c] [1,2,5] thiadiazolidyl自由基阴离子的反磁性π-二聚体的结晶状态：[（Me2N）（ 2）CC（NMe2）（2）]（2 +）[（C2N4S2）（2）]（2-）盐
4. Anion-exchange reaction of Friedel’s salt between Cl-and SO4~(2-) or CrO4~(2-) [C] . OHYA J., HIRANO M., SANGO H. International Congress on the Chemistry of Cement . 2011

机译：Friedel盐之间的阴离子交换反应Cl-and SO4〜（2-）或CRO4〜（2-）
5. Chemistry of the inner sulfonium salts of dodecahydrododecaborate (2-) anion. [D] . Kultyshev, Roman G. 2001

机译：十二氢十二硼酸酯（2-）阴离子的内部salts盐的化学性质。
6. An unexpected rhenium(IV)–rhenium(VII) salt: Co(NH3)63ReVIIO4ReIVF64·6H2O [O] . James Louis–Jean, Samundeeswari Mariappan Balasekaran, Adelheid Hagenbach, 2019

机译：意外的rh（IV）-hen（VII）盐：Co（NH3）6 3 ReVIIO4 ReIVF6 4·6H2O
7. Studies of β-diketone complexes of rhenium. IX. The preparation and characterization of salts of the trans-dihalobis(pentane-2,4-dionato)rhenate(III) anion and an improved preparation of tris(pentane-2,4-dionato)rhenium(III) [O] . C. J. L. Lock, C. N. Murphy, M. L. Turner 1979

机译：铼β-Diketone复合物的研究。 IX。反式二卤石（戊烷-2,4-二乙基）renate（III）阴离子的制备和表征和改进的Tris（戊烷-2,4-二乙酯）铼（III）的制剂
8. Search for Metastable Triplet States of d(sup o) Tetroxo Anions: A Study of VO4(3-), MoO4(2-) and Cr2O7(2-) by EPR with Optical Detection at Low Temperatures [R] . Barendswaard, W. 1986

机译：寻找d（sup o）Tetroxo阴离子的亚稳态三重态：通过EpR在低温下进行光学检测的VO4（3-），moO4（2-）和Cr2O7（2-）的研究

Remarkably stable dinuclear, diamagnetic rhenium(VI) salts with the [ReOCl4OReOCl4](2-) anion

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