Supramolecular NHC ligands: on the influence of Zn~(II)-templates on theactivity of Rh~I(cod) complexes in `carbene polymerization

Miguel Rubio; Erica Jellema; Maxime A. Siegler; Anthony L. Spek; Joost N. H. Reek; Bas de Bruin

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Supramolecular NHC ligands: on the influence of Zn~(II)-templates on theactivity of Rh~I(cod) complexes in `carbene polymerization

机译：超分子NHC配体：Zn〜（II）-模板对卡宾聚合中Rh〜I（cod）配合物活性的影响

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New RhI(cod) complexes of N-heterocyclic carbene ligands containing a pending pyridyl moiety forsubsequent binding of ZnII-templates were designed for supramolecular catalyst control in `carbenepolymerization' reactions. ZnII-templates indeed have an influence on the yields and the polymermolecular weights (and weight distributions) produced by these `supramolecular assemblies'. However,control experiments reveal that the effect of the ZnII-template on the polymerization results is generaland not due to the assembly formation.

机译：N-杂环卡宾配体的新RhI（cod）络合物包含待定的吡啶基部分，用于随后结合ZnII-模板，被设计用于“卡宾聚合”反应中的超分子催化剂控制。 ZnII模板确实会对这些“超分子组装体”产生的产率和聚合物分子量（和重量分布）产生影响。然而，对照实验表明，ZnII-模板对聚合结果的影响是普遍的，而不是由于组装体的形成。

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《Dalton transactions: An international journal of inorganic chemistry》 |2009年第41期|共7页
作者
Miguel Rubio; Erica Jellema; Maxime A. Siegler; Anthony L. Spek; Joost N. H. Reek; Bas de Bruin;
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正文语种 eng
中图分类化学;
关键词
Supramolecular; NHC ligands; on the influence;

机译：超分子;NHC配体;影响;

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1. Supramolecular NHC ligands: on the influence of Zn~(II)-templates on theactivity of Rh~I(cod) complexes in `carbene polymerization [J] . Miguel Rubio, Erica Jellema, Maxime A. Siegler, Dalton transactions: An international journal of inorganic chemistry . 2009,第41期

机译：超分子NHC配体：Zn〜（II）-模板对卡宾聚合中Rh〜I（cod）配合物活性的影响
2. Preparation of Au(I),Ag(I),and Pd(II) N-Heterocyclic Carbene Complexes Utilizing a Methylpyridyl-Substituted NHC Ligand.Formation of a Luminescent Coordination Polymer [J] . Vincent J.Catalano, Anthony 0.Etogo Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2007,第14期

机译：利用甲基吡啶基取代的NHC配体制备Au（I），Ag（I）和Pd（II）N-杂环碳烯配合物。发光配位聚合物的形成
3. Metal ion influences distortion of the ligand in the structure of [M{2-MeO(O)CC6H4NHC(S) NP(S)-(OiPr)(2)}(2)] (M = Zn-II, Cd-II) complexes: a driving force for intermolecular aggregation [J] . Safin Damir A., Babashkina Maria G., Bolte Michael, Dalton transactions: An international journal of inorganic chemistry . 2015,第31期

机译：金属离子影响[M {2-MeO（O）CC6H4NHC（S）NP（S）-（OiPr）（2）}（2）]结构中配体的变形（M = Zn-II，Cd-II ）复合物：分子间聚集的驱动力
4. Synthesis of Nickel(II) N-Heterocyclic Carbene (NHC) Complexes, Catalyzing Cross-coupling Reactions [C] . Kouki Matsubara, Keita Ueno Symposium on Organometallic Chemistry . 2006

机译：合成镍（II）正杂环基石（NHC）复合物，催化交叉偶联反应
5. Green synthesis of nitrogen heterocyclic carbene (NHC) ligands for NHC-stabilized rhenium polyhydride catalysts [D] . Chitikireddi, Vidya 2011

机译：用于NHC稳定的poly多价催化剂的氮杂环卡宾（NHC）配体的绿色合成
6. XAS Analysis of Reactions of (Arylimido)vanadium(V)Dichloride Complexes Containing Anionic NHC That Contains a WeaklyCoordinating B(C6F5)3 Moiety (WCA-NHC)or Phenoxide Ligands with Al Alkyls: A Potential Ethylene PolymerizationCatalyst with WCA-NHC Ligands [O] . Kotohiro Nomura, Go Nagai, Itsuki Izawa, 2019

机译：（Arylimido）钒（V）反应的XAS分析含有阴离子型NHC的二氯化物络合物含量微弱协调B（C6F5）3部分（WCA-NHC）或酚醛配体与烷基铝：潜在的乙烯聚合WCA-NHC配体的催化剂
7. Supramolecular NHC ligands: On the influence of Zn-II-templates on the activity of Rh-I(cod) complexes in 'carbene polymerization' [O] . Rubio, M., Jellema, E., Siegler, M.A., 2009

机译：超分子NHC配体：在“卡宾聚合”中Zn-II-模板对Rh-I（cod）配合物活性的影响
8. Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 90. (1) Synthesis of the Complexes (W2M2(mu-CO)(mu-CMe)(mu3-CMe)-(Mu-PPh2)2(CO)3(eta-C5H5)2) (M = Rh or Ir) and Related Tetra- and Penta-nuclear Metal Compounds: Interconversion of Ketenyl and Lambda(5) -Phospha-alkyne Ligands Bridging Tungsten-Rhodium Bonds. [R] . Davies, S. J., Stone, F. G. 1989

机译：具有桥接卡宾或卡宾配体的多核金属配合物的化学。部分90.（1）配合物的合成（W2m2（mu-CO）（mu-Cme）（mu3-Cme） - （mu-pph2）2（CO）3（eta-C5H5）2）（m = Rh或Ir）和相关的四核和五核金属化合物：Ketenyl和Lambda（5）-phospha-alkyne配体桥联钨 - 铑键的相互转化。

Supramolecular NHC ligands: on the influence of Zn~(II)-templates on theactivity of Rh~I(cod) complexes in `carbene polymerization

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