Intermediate spin ground state of an isosceles triangular [Mn~II3] complex

Sima Haddadpour; Heiko Niedermeyer; Rodolphe Clirac; Stefanie Dehnen

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Intermediate spin ground state of an isosceles triangular [Mn~II3] complex

机译：等腰三角形[Mn〜II3]配合物的中间自旋基态

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[{Mn(tmeda)}_3{GeSe_3(OMe)}_2] (1), synthesized by the re-action of [K_4(H_2O)_3][Ge_2Se_6]with MnCl_2.4H_20 in MeOH-tmeda (tmeda = N,N,N',N'-tetramethyl-1,2-diaminoethane),exhibits an isosceles triangular arrangement of Mn~(2+) ions thatare antiferromagnetically coupled with an S = 3/2 groundstate.

机译：[{Mn（tmeda）} _ 3 {GeSe_3（OMe）} _ 2]（1），由[K_4（H_2O）_3] [Ge_2Se_6]与MnCl_2.4H_20在MeOH-tmeda中反应制得（tmeda = N， N，N'，N'-四甲基-1,2-二氨基乙烷）具有Mn〜（2+）离子的等腰三角形排列，这些离子与S = 3/2基态反铁磁耦合。

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来源
《Dalton transactions: An international journal of inorganic chemistry》 |2009年第39期|共3页
作者
Sima Haddadpour; Heiko Niedermeyer; Rodolphe Clirac; Stefanie Dehnen;
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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
Intermediate spin; ground state; complex;

机译：中级自旋基态复杂;

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1. Intermediate spin ground state of an isosceles triangular [Mn~II3] complex [J] . Sima Haddadpour, Heiko Niedermeyer, Rodolphe Clirac, Dalton transactions: An international journal of inorganic chemistry . 2009,第39期

机译：等腰三角形[Mn〜II3]配合物的中间自旋基态
2. Assembly of triangular trimetallic complexes by triamidophosphine ligands: Spin-frustrated Mn2+ plaquettes and diamagnetic Mg2+ analogues with a combined through-space, through-bond pathway for P-31-P-31 spin-spin coupling [J] . Hatnean JA, Raturi R, Lefebvre J, Journal of the American Chemical Society . 2006,第46期

机译：由三酰胺膦配体组装的三角形三金属配合物：自旋受阻的Mn2 +小球和抗磁性Mg2 +类似物，具有用于P-31-P-31自旋-自旋耦合的结合的贯穿空间，贯穿键路径
3. Two new mixed-valence manganese complexes of formula [Mn_4O_2(X-benzoato)_7(bpy)_2] (X=2-Cl,2-Br) and the Crystal structure of the 2-Cl complex:Ground-State spin variability in the [Mn_4O_2]~(7+) complexes [J] . Belen Albela, Mohamed Salah El Fallah, Joan Ribas, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2001,第5期

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Intermediate spin ground state of an isosceles triangular [Mn~II3] complex

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