Immobilization of monomeric organometallic molybdenum oxo and carbonyl complexes and their application in epoxidation reactions

Jain KR; Kuhn FE

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Immobilization of monomeric organometallic molybdenum oxo and carbonyl complexes and their application in epoxidation reactions

机译：单体有机金属钼和羰基配合物的固定化及其在环氧化反应中的应用

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Various oxomolybdenum complexes are efficient and selective homogeneous catalysts in the presence of organic hydroperoxides. The increasing interest in the heterogenisation of such catalysts has led to an increased interest in finding suitable support materials for the complexes. These supports include ionic liquids, mesoporous materials and zeolites to name a few. Several methods are used to anchor the catalyst depending on the nature of the carrier material. The supported catalysts combine properties of homogeneous catalysts such as reactivity, control and selectivity with those of heterogeneous catalysts such as enhanced stability and recyclability.

机译：在有机氢过氧化物的存在下，各种氧钼配合物是有效且选择性的均相催化剂。对这种催化剂的异质化的日益增长的兴趣导致对寻找用于络合物的合适的载体材料的日益增长的兴趣。这些载体包括离子液体，中孔材料和沸石等。根据载体材料的性质，使用几种方法来锚定催化剂。负载型催化剂将均相催化剂的性能（如反应性，控制性和选择性）与非均相催化剂的性能（如增强的稳定性和可回收性）结合在一起。

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《Dalton transactions: An international journal of inorganic chemistry》 |2008年第17期|共7页
作者
Jain KR; Kuhn FE;
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正文语种 eng
中图分类化学;
关键词
IMIDAZOLE-CONTAINING POLYMERS; MESOPOROUS MCM-41 MATERIALS; TEMPERATURE IONIC LIQUID; ALKENE EPOXIDATIONS; OLEFIN EPOXIDATION; DIOXOMOLYBDENUM(VI) COMPLEXES; CATALYTIC APPLICATION; CYCLOHEXENE EPOXIDATION; TRANSFER MOLYBDOENZYMES; EFFICIENT CATALYSTS;

机译：含咪唑的聚合物;介孔的MCM-41材料;温度离子液体;烯烃的环氧化;烯烃的环氧化;二氧钼（VI）络合物;催化应用;环己烯的环氧化;转移的多钼基苯甲酸酯;有效的;

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1. Immobilization of monomeric organometallic molybdenum oxo and carbonyl complexes and their application in epoxidation reactions [J] . Jain KR, Kuhn FE Dalton transactions: An international journal of inorganic chemistry . 2008,第17期

机译：单体有机金属钼和羰基配合物的固定化及其在环氧化反应中的应用
2. Chemistry and catalytic activity of molybdenum(VI)-pyrazolylpyridine complexes in olefin epoxidation. Crystal structures of monomeric dioxo, dioxo-μ-oxo, and oxodiperoxo derivatives [J] . Coelho A.C., Nolasco M., Balula S.S., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2011,第2期

机译：钼（VI）-吡唑基吡啶配合物在烯烃环氧化中的化学和催化活性单体二氧，二氧-μ-氧和氧二过氧衍生物的晶体结构
3. The reactions of the monodentate organometallic phosphines [MI2(CO)(3){MeC(CH2PPh2)(3)-P,P '}] (M = Mo, W) with pi-allyl molybdenum(II) complexes and iron(O) and iron(II) carbonyl complexes [J] . Baker PK., Al-Jahdali M. Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2002,第22期

机译：单齿有机金属膦[MI2（CO）（3）{MeC（CH2PPh2）（3）-P，P'}]（M = Mo，W）与π-烯丙基钼（II）配合物和铁（O）的反应）和羰基铁（II）配合物
4. Sequential Hydrocarbon C-H Bond Activations by 16-Electron Organometallic Complexes of Molybdenum and Tungsten [C] . Peter Legzdins, Craig B. Pamplin American Chemical Society National Meeting . 2004

机译：钼和钨的16型电子有机金属配合物顺序烃C-H键活化
5. I. Organometallic enantiomeric scaffolding: Total synthesis of (-)-adaline and (-)-adalinine using a key 5-oxo-pyridinyl molybdenum scaffold and featuring a semipinacol rearrangment/1,5-'Michael-like' sequence. II. Exchange reactions of 1-alkoxy and 1-sulfonyloxy eta3-allyl molybdenum complexes [D] . Coombs, Thomas C. 2008

机译：I.有机金属对映体骨架：使用关键的5-氧代-吡啶基钼骨架并具有半频哪醇重排/ 1,5-'Michael-like'序列的（-）-adaline和（-）-adalinine的全合成。二。 1-烷氧基和1-磺酰氧基η3-烯丙基钼配合物的交换反应
6. A Comparative Study of Molybdenum Carbonyl and Oxomolybdenum Derivatives Bearing 123-Triazole or 124-Triazole in Catalytic Olefin Epoxidation [O] . Lucie S. Nogueira, Patrícia Neves, Ana C. Gomes, 2019

机译：含123-三唑或124-三唑的钼羰基和氧钼衍生物在催化烯烃环氧化中的比较研究
7. New insights into the mechanism of oxodiperoxomolybdenum catalysed olefin epoxidation and the crystal structures of several oxo–peroxo molybdenum complexes [O] . Herbert Matthew, Montilla Ramos Francisco Javier, Álvarez González Eleuterio, 2012

机译：氧二过氧钼钼催化烯烃环氧化机理的新见解和几种氧-过氧钼配合物的晶体结构
8. Kinetic Study of the Oxygen-Transfer Reactions from the Oxo Diperoxo Complexes of Molybdenum(VI) and Tungsten(VI) to (Thiolato)- and (Sulfenato)cobalt(III) Complexes [R] . Ghiron, A. F., Thompson, R. C. 1988

机译：钼（VI）和钨（VI）与（硫代） - （sulfenato）钴（III）配合物的氧代二过氧配合物的氧转移反应动力学研究

Immobilization of monomeric organometallic molybdenum oxo and carbonyl complexes and their application in epoxidation reactions

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