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首页> 外文期刊>Zeitschrift fur Kristallographie. New crystal structures >Crystal structures of α - and β-antimony dimercury tetrachloroaluminate, SbHg_2AlCl_4
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Crystal structures of α - and β-antimony dimercury tetrachloroaluminate, SbHg_2AlCl_4

机译:α-和β-锑二甲基四氯铝酸盐SbHg_2AlCl_4的晶体结构

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摘要

α-[SbHg2]AlCU was obtained by annealing a mixture (> 99.5 %, Acros), Sb (Shot, 1-3 mm, 99.999%, HERAEUS) and Al (pieces: 2.5 -3.9 mm, 99.999 %, Chempur) in the ratio 2:1:1 at 493 K for seven days. The dark red crystalline product is highly air sensitive and does not show any contamination phases in standard X-ray powder diagrams. Single crystals for X-ray studies were isolated under dry argon and transferred into sealed capillaries.
机译:α-[SbHg2] AlCU是通过在以下温度下对混合物(> 99.5%,Acros),Sb(Shot,1-3 mm,99.999%,HERAEUS)和Al(件:2.5 -3.9 mm,99.999%,Chempur)进行退火而获得的。在493 K上以2:1:1的比例持续7天。暗红色结晶产物对空气高度敏感,在标准X射线粉末图中未显示任何污染相。在干燥的氩气下分离用于X射线研究的单晶,并转移到密封的毛细管中。

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