Spectroscopic investigation and oxidation of the anticholinergic drug atropine sulfate monohydrate by hexacyanoferrate(III) in aqueous alkaline media: a mechanistic approach

Manjunath METI; Sharanappa NANDIBEWOOR; Shivamurti CHIMATADAR

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Spectroscopic investigation and oxidation of the anticholinergic drug atropine sulfate monohydrate by hexacyanoferrate(III) in aqueous alkaline media: a mechanistic approach

机译：六氰合铁酸盐（III）在碱性介质中的光谱研究和抗胆碱药硫酸阿托品硫酸盐一水合物的氧化：一种机械方法

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The oxidation of the anticholinergic drug atropine sulfate monohydrate by hexacyanoferrate(III) in aqueous alkaline media was investigated spectrophotometrically by monitoring the decrease in absorbance of hexacyanoferrate(III) (HCF(III)). Oxidation products were identified. The oxidation mechanism was proposed from kinetic studies. The reaction constants involved in the different steps of the mechanism were calculated. The effects of added products, ionic strength, and dielectric constant of the reaction were investigated. The polymerization test revealed that oxidation occurred with intervention of free radicals. The activation parameters were evaluated.

机译：通过监测六氰合铁酸盐（III）（HCF（III））吸光度的降低，用分光光度法研究了在水性碱性介质中六氰合铁酸盐（III）对抗胆碱药物阿托品硫酸盐一水合物的氧化。确定了氧化产物。氧化机理由动力学研究提出。计算了机理不同步骤中涉及的反应常数。研究了添加产物，离子强度和反应介电常数的影响。聚合试验表明，氧化是在自由基的干预下发生的。评估激活参数。

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《Turkish journal of chemistry》 |2014年第3期|共11页
作者
Manjunath METI; Sharanappa NANDIBEWOOR; Shivamurti CHIMATADAR;
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正文语种 eng
中图分类化学;
关键词
Kinetics of oxidation; mechanism; hexacyanoferrate(III); atropine sulfate;

机译：氧化动力学;机理;高铁酸六氰（III）;硫酸阿托品;

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1. Spectroscopic Investigation and Reactivities of Ruthenium(III) Catalyzed Oxidation of Anticholinergic Drug Atropine Sulfate Monohydrate by Hexacyanoferrate(III) in Aqueous Alkaline Media: A Mechanistic Approach [J] . Manjunath D. Meti, Sharanappa T. Nandibewoor, Shivamurti A. Chimatadar Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry . 2014,第1a3期

机译：六氰基铁酸盐（III）在碱性介质中钌（III）催化氧化抗胆碱能药物阿托品硫酸盐一水合物的光谱研究和反应性：一种机械方法
2. Spectroscopic investigation and oxidation of the anticholinergic drug atropine sulfate monohydrate by hexacyanoferrate(III) in aqueous alkaline media: a mechanistic approach [J] . Manjunath METI, Sharanappa NANDIBEWOOR, Shivamurti CHIMATADAR Turkish journal of chemistry . 2014,第3期

机译：六氰合铁酸盐（III）在碱性介质中的光谱研究和抗胆碱药硫酸阿托品硫酸盐一水合物的氧化：一种机械方法
3. Spectroscopic investigation and oxidation of the anticholinergic drug atropine sulfate monohydrate by hexacyanoferrate(III) in aqueous alkaline media: a mechanistic approach [J] . MANJUNATH METI, SHARANAPPA NANDIBEWOOR, SHIVAMURTI CHIMATADAR Turkish journal of chemistry . 2014,第3期

机译：六氰合铁酸盐（III）在碱性介质中的光谱研究和抗胆碱药硫酸阿托品硫酸盐一水合物的氧化：一种机械方法
4. MECHANISTIC INVESTIGATIONS OF OXIDATION OF PURINE AND PYRIMIDINE BASE COMPONENTS OF NUCLEIC ACIDS BY BROMAMINE-B IN AQUEOUS ALKALINE MEDIUM : A KINETIC APPROACH [C] . Nirmala Vaz, Puttaswamy 3rd International Symposium on Reaction Kinetics and the Development and Operation of Catalytic Processes, Apr 22-25, 2001, Oostende, Belgium . 2001

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机译：第一部分：丙烷在三氟甲苯磺酸单羟基磺酸盐溶液中催化的离子交换膜上的氧化。第二部分：使用铅作为分析目的的电极材料。第三部分：苯自由基阴离子中间体对苯的电还原的影响。
6. Mechanistic studies of uncatalyzed and ruthenium(III)-catalyzed oxidation of the antibiotic drug chloramphenicol by hexacyanoferrate(III) in aqueous alkaline medium: a comparative kinetic study [O] . M. D. Meti, K. S. Byadagi, S. T. Nandibewoor, -1

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7. Spectroscopic investigation and oxidation of the anticholinergic drug atropine sulfate monohydrate by hexacyanoferrate(III) in aqueous alkaline media: a mechanistic approach [O] . Manjunath METI, Sharanappa NANDIBEWOOR, Shivamurti CHIMATADAR 2014

机译：六氰基甲醛（III）在碱性介质中的光谱研究和氧化抗胆碱能药物硫酸盐一水合物：机械方法
8. Spectroscopic Studies of the Passive Film on Alkali and Alkaline Earth Metals in Non-Aqueous Solvents: A Surface Science Approach, Final Report. [R] . Herrera-Fierro, P., Xing, X., Chottiner, G., 1988

机译：非水溶剂中碱金属和碱土金属被动膜的光谱研究：表面科学方法，最终报告。

Spectroscopic investigation and oxidation of the anticholinergic drug atropine sulfate monohydrate by hexacyanoferrate(III) in aqueous alkaline media: a mechanistic approach

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