PREPARATION AND STRUCTURE OF BICYCLOALKANE-CONDENSEDARYLDIAZIRIDINES ACCOMPANIED BY PYRIMIDINES

Pal Sohar; Antal Csampai; Reijo Sillanpaa

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PREPARATION AND STRUCTURE OF BICYCLOALKANE-CONDENSEDARYLDIAZIRIDINES ACCOMPANIED BY PYRIMIDINES

机译：嘧啶伴有双环烷-稠合二氮杂二氮杂胺的制备与结构

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Di-exo- and di-endo-2-aminonorbornane/enemethanamines 1-3, di-exo-oxanorbornene derivative 4 and cis-cyclohexane and trans-4-cyclohexene analogues 5, 6 were reacted with p-chlorobenzaldehyde in the presence of iV-bromosuccinimide in dichloromethane.Via the reactions of 1-6, condensed diaziridines 7-12 accompanied by pyrimidine derivatives 13-16 were prepared after isolation with column chromatography.The mechanisms proposed for alternative transformations were supported by DFT calculations.The structures of the new compounds were proved by IR and NMR spectroscopy and, for 7,9 and 12, also by means of X-ray crystallography.

机译：在存在iV的情况下，将二-exo-和di-endo-2-aminonorbornaneane / enemethanamines 1-3，di-exo-oxanorbornene衍生物4和顺式环己烷和反式-4-环己烯类似物5、6与对氯苯甲醛反应溴化琥珀酰亚胺在二氯甲烷中的分离。通过柱色谱分离，制备1-6的缩合二氮丙啶7-12与嘧啶衍生物13-16的反应，并通过DFT计算支持了拟议的其他转化机理。通过IR和NMR光谱证明了这些化合物，并且对于7,9和12，还通过X射线晶体学证明。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry》 |2007年第6期|共12页
作者
Pal Sohar; Antal Csampai; Reijo Sillanpaa;
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中图分类杂环化合物;
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1. PREPARATION AND STRUCTURE OF BICYCLOALKANE-CONDENSEDARYLDIAZIRIDINES ACCOMPANIED BY PYRIMIDINES [J] . Pal Sohar, Antal Csampai, Reijo Sillanpaa Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2007,第6期

机译：嘧啶伴有双环烷-稠合二氮杂二氮杂胺的制备与结构
2. Preparation, Properties, and X-ray Structures of Bis(10-methyl-9-methyleneacridan)-type Electron Donors with a Thiophene, Bithiophene, or Terthiophene Skeleton: Redox Switching of Thiophene-Thienoquinoid Structure Accompanied by UV-vis-NIR Electrochromic Response [J] . Takanori Suzuki, Yuuki Hoshiyama, Kazuhisa Wada Chemistry Letters . 2013,第9期

机译：具有噻吩，联噻吩或三噻吩骨架的双（10-甲基-9-亚甲基ac啶）型电子给体的制备，性质和X射线结构：紫外-可见-近红外电致变色反应伴随着噻吩-噻吩醌结构的氧化还原转换
3. ZINC, CADMIUM, AND MERCURY COMPLEXES OF 5,7-DIMETHYL[1,2,4]TRIAZOLO[1,5-A]PYRIMIDINE (DMTP) - PREPARATION, SPECTROSCOPIC CHARACTERIZATION, AND BIOLOGICAL ACTIVITY - X-RAY CRYSTAL STRUCTURES OF [ZN(DMTP)(2)BR-2], [HG(DMTP)(2)CL-2], AND [HDMTP](2)[CDBR [J] . Salas JM., Rahmani A., Faure R., Journal of Inorganic Biochemistry: An Interdisciplinary Journal . 1996,第4期

机译：5,7-二甲基[1,2,4]三唑并[1,5-A]嘧啶（DMTP）的锌，镉和汞络合物-制备，光谱表征和生物活性-[ZN]的X射线晶体结构（DMTP）（2）BR-2]，[HG（DMTP）（2）CL-2]和[HDMTP]（2）[CDBR
4. Structures and Magnetic Properties of Pyrimidine-Bridged Transition-Metal Complexes [C] . Takashi Nogami, Takayuki Ishida China-Japan Joint Symposium on Conduction and Photoconduction in Organic Solids and Related Phenomena . 2000

机译：嘧啶桥接过渡 - 金属配合物的结构和磁性性能
5. Structured topic models: Jointly modeling words and their accompanying modalities. [D] . Wang, Xuerui. 2009

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6. Report on Dr P. N. Gerrards Preparations accompanying the foregoing communication [O] . C. M. Wenyon 1906

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7. Preparation and Crystal Structure of New Gold(I) Complexes Linked to Pyrimidines [O] . Takashi Amagai, T. Ken Miyamoto, Hikaru Ichida, 1989

机译：与嘧啶有关的新金（I）复合物的制备和晶体结构

PREPARATION AND STRUCTURE OF BICYCLOALKANE-CONDENSEDARYLDIAZIRIDINES ACCOMPANIED BY PYRIMIDINES

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