首页> 外文期刊>Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry >THE REGIOCHEMISTRY OF THE o-CLAISEN REARRANGEMENT OF BIS-(ALLOXY)POLYCYCLIC AROMATICS
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THE REGIOCHEMISTRY OF THE o-CLAISEN REARRANGEMENT OF BIS-(ALLOXY)POLYCYCLIC AROMATICS

机译:BIS-(合金)多环芳族化合物邻-克莱森重排的区域化学

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摘要

The o-Claisen rearrangement of bis-(allyloxy)naphthalenes,anthracenes and phenanthrenes is regiospecific and is consistent with resonance theory and molecular orbital calculations.While the o-Claisen rearrangement of allyl phenyl ethers has been rigorously studied,1 the rearrangement of bis-allyl aryl ethers has been limited to the ethers of hydroquinone(l),resorcinol(2),and 2,6-dihydroxynaphthalene(3).
机译:双(烯丙氧基)萘,蒽和菲的o-Claisen重排具有区域特异性,并且与共振理论和分子轨道计算相符。尽管已对烯丙基苯基醚的o-Claisen重排进行了严格的研究1烯丙基芳基醚仅限于氢醌(1),间苯二酚(2)和2,6-二羟基萘(3)的醚。

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