CHEMOSELECTIVE SYNTHESIS OF NEW DIBENZO[d,f]-1,3-DIOXEPINES AND 12H-DIBENZO[d,g]-1,3-DIOXOCINES

Graziella Tocco; Michela Begala; Gabriele Meli

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CHEMOSELECTIVE SYNTHESIS OF NEW DIBENZO[d,f]-1,3-DIOXEPINES AND 12H-DIBENZO[d,g]-1,3-DIOXOCINES

机译：化学合成新的二苯并[d，f] -1,3-二恶庚因和12H-二苯并[d，g] -1,3-二恶辛酸

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A new series of dibenzodioxepine and dibenzodioxocine derivatives was prepared starting from aliphatic and aromatic aldehydes,underlining the chemoselectivity of both the catalyst and the biphenol,also confirming the importance of the hydrogen atom in a position to the carbonyl group.

机译：从脂肪族和芳香族醛开始，制备了一系列新的二苯并二氧杂环庚烷和二苯并二氧杂环丁烷衍生物，突显了催化剂和双酚的化学选择性，也证实了氢原子在羰基上的重要性。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry》 |2007年第3期|共11页
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Graziella Tocco; Michela Begala; Gabriele Meli;
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1. CHEMOSELECTIVE SYNTHESIS OF NEW DIBENZO[d,f]-1,3-DIOXEPINES AND 12H-DIBENZO[d,g]-1,3-DIOXOCINES [J] . Graziella Tocco, Michela Begala, Gabriele Meli Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2007,第3期

机译：化学合成新的二苯并[d，f] -1,3-二恶庚因和12H-二苯并[d，g] -1,3-二恶辛酸
2. Indium(III)chloride catalyzed one step synthesis of some new dibenzo(d,f)(l,3)dioxepines and 12H-dibenzo(d,g)(l,3)dioxocin derivatives [J] . Graziella Tocco, Michela Begala, Giovanna Delogu, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2004,第37期

机译：氯化铟（III）催化一步合成一些新的二苯并（d，f）（l，3）二氧杂环庚烷和12H-二苯并（d，g）（l，3）二氧杂环丁烷衍生物
3. Synthesis of 6,12-Di(adamantane-2'-spiro)-6H,12H-dibenzo[b,f][1,5]dioxocine [J] . V. A. Osyanin, Yu. V. Popova, Yu.N. Klimochkin Russian Journal of Organic Chemistry . 2010,第2期

机译：6,12-二（金刚烷-2'-螺）-6H，12H-二苯并[b，f] [1,5]二氧嘧啶的合成
4. Synthesis and characterization of a cross-linking monomer based on 1,3-diallyl-1,3-dibicyclo4.2.0octa-1,3,5-trien-3-yl-1,3-dimethyl-siloxane [C] . K S Levchenko, E G Adamov, D U Demin, International Russian-Chinese Symposium "New Materials and Technologies" . 2020

机译：基于1,3-二烯丙基-1,3-Di的交联单体的合成与表征4.2.0八乙-1,3,5-三烯-3-基 - 1,3-二甲基 - 硅氧烷
5. I. Stereoselective Synthesis of 1,3-Diamino-2-ols via Allene Oxidation. II. Tunable, Chemoselective Silver(I)-Catalyzed Nitrene Transfer Reactions: Development and Mechanistic Study. [D] . Weatherly, Cale Daniel. 2015

机译：I.通过丙二烯氧化的立体选择性合成1，3-二氨基-2-醇。二。可调谐的，化学选择性的银（I）催化的硝基转移反应：发展和机理研究。
6. Bis{μ-1,3-bis[2-(5-bromo-2-oxidobenzylideneamino)ethyl]-2-(5-bromo-2-oxidophenyl)-1,3-imidazolidine}dineodymium(III) N,N-dimethylformamide hexasolvate [O] . Qing-Fan Xie, Miao-Ling Huang, Yan-Min Chen 2016

机译：双{μ-1,3-双[2-（5-溴-2-氧化苄叉亚氨基）乙基] -2-（5-溴-2-氧化苯基）-1,3-咪唑烷}钕（III）N，N-二甲基甲酰胺六溶剂化物
7. 2′,10′-Dibromospiro[cylohexane-1,6-dibenzo[d,f][1,3]dioxepine] [O] . Cheng-Bo Zhang, Hai-Quan Zhang, Qing-Shan Li, 2010

机译：2及＃8242;，10安培;＃8242; -Dibromospiro [环己烷-1,6 - 二苯并[d，f]的[1,3]二氧杂环庚烯]
8. Reaction of E,1,4-poly(2-triethylsilyl-1,3-butadiene) with Bromine. Stereoselective Synthesis of Z-1,4-poly(2-bromo-1,3-butadiene) [R] . Jiang, W., Weber, W. P. 1988

机译：E，1,4-聚（2-三乙基甲硅烷基-1,3-丁二烯）与溴的反应。立体选择性合成Z-1,4-聚（2-溴-1,3-丁二烯）

CHEMOSELECTIVE SYNTHESIS OF NEW DIBENZO[d,f]-1,3-DIOXEPINES AND 12H-DIBENZO[d,g]-1,3-DIOXOCINES

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