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Using transgenic poplars to elucidate the relationship between the structure and the thermal properties of lignins

机译:使用转基因杨树阐明木质素的结构与热性质之间的关系

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摘要

In an attempt to draw relationships between the molecular structure and the thermal behavior of lignins, thermomechanical analyses were run on six milled wood and enzyme poplar lignin fractions prepared from genetically modified and control woods. All the lignin samples displayed similar thermal profiles with a clear inflection point assigned to the glass transition point. The temperature (T-g) at which this transition occurs showed large variations from 170 to 190 degreesC, depending both on the genetic modification and on the age of the tree. These variations were found to be closely related to the condensation degree of lignins evaluated by thioacidolysis.
机译:为了画出木质素的分子结构和热行为之间的关系,对六种经过碾磨的木材和由转基因和对照木材制备的酶杨木木质素级分进行了热机械分析。所有木质素样品均显示出相似的热曲线,并为玻璃化转变点指定了清晰的拐点。发生这种转变的温度(T-g)在170至190摄氏度之间显示出较大的差异,这取决于基因的修饰和树的年龄。发现这些变化与通过硫代酸解评估的木质素的缩合度密切相关。

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