Electroreduction of nitrobenzene to p-aminophenol using voltammetric and semipilot scale preparative electrolysis techniques

Polat K.; Aksu ML.; Pekel AT.

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Electroreduction of nitrobenzene to p-aminophenol using voltammetric and semipilot scale preparative electrolysis techniques

机译：伏安法和半自动规模制备电解技术将硝基苯电还原为对氨基苯酚

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This paper describes an investigation of the reduction of nitrobenzene to p-aminophenol by the use of CV, RDE and preparative electrolysis with Cu and Cu(Hg) electrodes. The preparative electrolyses of nitrobenzene were carried out at controlled current and controlled potential conditions using copper and amalgamated copper using a new semipilot (laboratory) scale system in the absence of an organic cosolvent. The effects of redox reagents and the concentration of nitrobenzene in catholyte added to the medium were also examined. The best results were obtained with 2.3% BiCl3 at nitrobenzene concentration of 0.144 g cm(-)3 catholyte. The most suitable electrode material was found to be amalgamated copper and the reduction of nitrobenzene to p-aminophenol was found to follow an ECE mechanism. [References: 29]

机译：本文介绍了通过使用CV，RDE以及使用Cu和Cu（Hg）电极进行制备性电解将硝基苯还原为对氨基苯酚的研究。在不存在有机助溶剂的情况下，使用新的半自动（实验室）规模系统，在铜和汞齐铜的控制电流和控制电位条件下，进行硝基苯的制备性电解。还检查了氧化还原试剂和添加到培养基中的阴极电解液中硝基苯浓度的影响。在硝基苯浓度为0.144 g cm（-）3阴极电解液时，使用2.3％BiCl3可获得最佳结果。发现最合适的电极材料是汞齐合的铜，并且发现硝基苯还原为对氨基苯酚遵循ECE机理。 [参考：29]

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《Journal of Applied Electrochemistry》 |2002年第2期|共7页
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Polat K.; Aksu ML.; Pekel AT.;
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正文语种 eng
中图分类电化学工业;物理化学（理论化学）、化学物理学;
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1. Electroreduction of nitrobenzene to p-aminophenol using voltammetric and semipilot scale preparative electrolysis techniques [J] . Polat K., Aksu ML., Pekel AT. Journal of Applied Electrochemistry . 2002,第2期

机译：伏安法和半自动规模制备电解技术将硝基苯电还原为对氨基苯酚
2. Green and large-scale preparation of reduced graphene oxide for electroreduction of nitrobenzene to p-aminophenol [J] . Wei Ming Liu, Xue Qin Wang, Cong Min Wang, Micro & Nano Letters, IET . 2016,第11期

机译：绿色和大规模制备还原氧化石墨烯以将硝基苯电还原为对氨基苯酚的方法
3. ELECTRO-ORGANIC CHEMISTRY OF FULLERENES .1. INDIRECT CATHODIC REDUCTION OF VIC-DIHALIDES AND PERFLUOROALKYL HALIDES USING C-60 AS MEDIATOR - CYCLIC VOLTAMMETRIC STUDY AND PREPARATIVE-SCALE ELECTROLYSIS [J] . Fuchigami T., Konno A., Kasuga M. Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry . 1996,第1a2期

机译：富勒烯的电子有机化学1。以C-60为介导的循环伏安研究和制备规模电解间接降低联苯和氟代烷基卤化物的含量。
4. Electroreduction of o-substituted Nitrobenzene on Cu-Hg Electrodes [C] . . 2005

机译：Cu-Hg电极上邻位取代硝基苯的电还原
5. Development of Potentiostat Platform for Complex Voltammetric Measurements and Self-Adjustable Electrolysis [D] . Chan, Yin Shing Gary. 2020

机译：大型伏安测量恒电位平台的开发及自调节电解
6. Studies in detoxication. 40. The metabolism of nitrobenzene in the rabbit. o- m- and p-Nitrophenols o- m- and p-aminophenols and 4-nitrocatechol as metabolites of nitrobenzene [O] . D. Robinson, J. N. Smith, R. T. Williams 1951

机译：解毒研究。 40.兔子体内硝基苯的代谢。邻间和对硝基苯酚邻间和对氨基苯酚和4-硝基邻苯二酚作为硝基苯的代谢物
7. Studies in detoxication. 40. The metabolism of nitrobenzene in the rabbit. o-, m- and p-Nitrophenols, o-, m- and p-aminophenols and 4-nitrocatechol as metabolites of nitrobenzene [O] . Robinson, D., Smith, J. N., Williams, R. T. 1951

机译：解毒研究。 40.兔子体内硝基苯的代谢。邻，间和对硝基苯酚，邻，间和对氨基苯酚和4-硝基邻苯二酚作为硝基苯的代谢物
8. Rapid, Portable Voltammetric Techniques for Performing Antioxidant, Total AcidNumber (TAN) and Total Base Number (TBN) Measurements [R] . Kauffman, R. E. 1996

机译：用于执行抗氧化剂，总酸值（TaN）和总碱值（TBN）测量的快速便携式伏安法技术

Electroreduction of nitrobenzene to p-aminophenol using voltammetric and semipilot scale preparative electrolysis techniques

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