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首页> 外文期刊>Journal of Applied Electrochemistry >Development of nitrogen-doped carbons using the hydrothermal method as electrode materials for vanadium redox flow batteries
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Development of nitrogen-doped carbons using the hydrothermal method as electrode materials for vanadium redox flow batteries

机译:使用水热法开发钒还原液流电池电极材料的氮掺杂碳

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摘要

Nitrogen-doped carbons are suggested as electrochemically active materials for V(IV)/V(V) redox couples for a vanadium redox flow battery (VRB). These materials were synthesized using a hydrothermal reaction of aqueous glucose solution in the presence of ethylenediamine as a nitrogen source. The physical and electrochemical properties of the nitrogen-doped carbons are characterized by cyclic voltammetry, high-resolution transmission electron microscopy and X-ray photoelectron spectrometry. These results reveal that the hydrothermal method is an effective way to synthesize high-content nitrogen-doped carbons. Nitrogen doping significantly improves catalytic activity and reversibility. Therefore, use of nitrogen-doped carbon is expected to increase the energy storage efficiency of VRBs.
机译:钒掺杂液流电池(VRB)的V(IV)/ V(V)氧化还原对被建议使用氮掺杂的碳作为电化学活性材料。在乙二胺作为氮源存在下,使用葡萄糖水溶液的水热反应合成了这些材料。氮掺杂碳的物理和电化学特性通过循环伏安法,高分辨率透射电子显微镜和X射线光电子能谱进行表征。这些结果表明,水热法是合成高含量氮掺杂碳的有效方法。氮掺杂显着提高了催化活性和可逆性。因此,期望使用掺杂氮的碳来增加VRB的能量存储效率。

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