Synthesis of poly(beta-pinene)-g-polystyrene from allylic brominated poly(beta-pinene)

Hui L.; Jiang L.

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Synthesis of poly(beta-pinene)-g-polystyrene from allylic brominated poly(beta-pinene)

机译：由烯丙基溴化聚（β-pine烯）合成聚（β-pine烯）-g-聚苯乙烯

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Poly(beta-pinene) was brominated by N-bromosuccinimide on the allylic carbons. Then the brominated product was activated by AlEt2Cl to initiate the polymerization of styrene to give a beta-pinene/styrene graft copolymer. AlEt2Cl was selected because it alone could not initiate the polymerization of styrene. The obtained graft copolymer was characterized by GPC, H-1-NMR, and DSC measurements, respectively. (C) 2000 John Wiley & Sons, Inc. [References: 4]

机译：聚（β-pine烯）被N-溴琥珀酰亚胺在烯丙基碳上溴化。然后，溴化产物被AlEt2Cl活化，引发苯乙烯的聚合反应，得到β-pine烯/苯乙烯接枝共聚物。选择AlEt2Cl是因为它本身不能引发苯乙烯的聚合。分别通过GPC，H-1-NMR和DSC测量来表征获得的接枝共聚物。（C）2000 John Wiley＆Sons，Inc. [参考：4]

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《Journal of Applied Polymer Science》 |2000年第5期|共5页
作者
Hui L.; Jiang L.;
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正文语种 eng
中图分类高分子化学（高聚物）;高分子化合物产品;有机化学;
关键词
Beta-pinene; Styrene; Graft copolymer; Bromination; Cationic isomerization polymerization; Beta-pinene; Copolymers;

机译：β-pine烯;苯乙烯;接枝共聚物;溴化;阳离子异构化聚合;β-pine烯;共聚物;

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专利

1. Synthesis of poly(beta-pinene)-g-polystyrene from allylic brominated poly(beta-pinene) [J] . Hui L., Jiang L. Journal of Applied Polymer Science . 2000,第5期

机译：由烯丙基溴化聚（β-pine烯）合成聚（β-pine烯）-g-聚苯乙烯
2. Synthesis of poly(beta-pinene)-b-polytetrahydrofuran from beta-pinene-based macroinitiator [J] . Lu J., Zhang RF., Li B., Polymer: The International Journal for the Science and Technology of Polymers . 2001,第10期

机译：基于β-pine烯的大分子引发剂合成聚（β-pine烯）-b-聚四氢呋喃
3. Photovoltaic Cells Involving the Nonconjugated Conductive Polymer, Iodine-Doped Poly(beta-pinene) [J] . Sangal M., Jaju S., Telang G., Journal of Macromolecular Science. Pure and Applied Chemistry . 2014,第10a12期

机译：涉及非共轭导电聚合物，碘掺杂聚（β-pine烯）的光伏电池
4. Brominated poly(isobutylene-co-para-methylstyrene) (BIMS)-clay nanocomposites: synthesis and characterization [C] . Madhuchhanda Maiti, Susmita Sadhu, Anil K. Bhowmick Symposium of International Rubber Conference vol.B; 20040921-25; Beijing(CN) . 2004

机译：溴化聚异丁烯-对-甲基苯乙烯共聚物（BIMS）-粘土纳米复合材料：合成与表征
5. A smog chamber study of mechanisms for beta-pinene oxidation by hydroxyl radicals. [D] . Auld, Janeen. 2009

机译：烟雾舱研究羟基自由基对β-pine烯氧化的机理。
6. Effects of beta-pinene on yeast membrane functions. [O] . S Uribe, J Ramirez, A Peña 1985

机译：β-pine烯对酵母膜功能的影响。
7. Synthesis of Kenaf Cellulose Supported Highly Active Poly(amidoxime) Palladium Complex and Its Application as a Reusable Catalyst for Allylic Arylation reactions [O] . Bablu Hira Mandal, Sarkar Shaheen M., Lutfor M. R., 2016

机译：红茶纤维素负载的高活性聚（ami肟）钯配合物的合成及其在烯丙基化反应中可重复使用的催化剂中的应用
8. Isomeric Poly(benzophenone)s: Synthesis of Highly Crystalline Poly(4,4'-benzophenone) and Amorphous Poly(2,5-benzophenone), a Soluble Poly(p-phenylene) Derivative [R] . Phillips, R. W., Sheares, V. V., Samulski, E. T., 1994

机译：异构聚（二苯甲酮）：高结晶聚（4,4'-二苯甲酮）和无定形聚（2,5-二苯甲酮），可溶性聚（对亚苯基）衍生物的合成

Synthesis of poly(beta-pinene)-g-polystyrene from allylic brominated poly(beta-pinene)

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