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Electron beam modification of filled fluorocarbon rubber

机译:填充氟碳橡胶的电子束改性

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The effect of electron beam irradiation on the properties of carbon black-, silica-, and clay-filled fluorocarbon rubber has been studied over a range of radiation doses, loadings, and nature of the fillers. Compared to the unfilled irradiated rubber, the tensile strength and modulus improve with a decrease in the particle size of the carbon black filler. Similar improvement in these properties is observed with an increase in both the radiation dose and the amount of the filler upto a certain level. The dynamic mechanical analysis reveal an increased glass transition temperature (T-g), a reduced value of the mechanical loss factor at T-g. and an enhanced dynamic storage modulus for the filled samples. The results are explained with the help of sol-gel analysis and volume fraction of rubber. It is observed that higher reinforcement in the case of the filled vulcanizate is obtained by electron beam modification, as compared to that using the conventional curing system. (C) 2000 John Wiley & Sons, Inc. [References: 20]
机译:在一定的辐射剂量,填充量和填充剂性质的范围内,已经研究了电子束辐照对炭黑,硅石和粘土填充的氟碳橡胶性能的影响。与未填充的辐照橡胶相比,抗张强度和模量随炭黑填料粒径的减小而提高。随着辐射剂量和填料量增加到一定水平,可以观察到这些性能的类似改善。动态力学分析表明玻璃化转变温度(T-g)升高,T-g处的机械损耗因子降低。并提高了填充样品的动态储能模量。通过溶胶-凝胶分析和橡胶的体积分数解释了结果。观察到,与使用常规固化系统相比,在填充的硫化橡胶的情况下,通过电子束改性获得了更高的增强。 (C)2000 John Wiley&Sons,Inc. [参考:20]

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