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New hydrogel containing sulfur compound prepared by gamma irradiation and its application for metal recovery

机译:γ辐射制备的新型含硫化合物水凝胶及其在金属回收中的应用

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摘要

A new hydrogel that contains sulfur is prepared by radiation polymerization and its application for recovery of Hg2+, Pb2+, Cd2+, and Cu2+ ions is discussed. The metal hydrogel complexes are isolated and characterized by using different spectroscopic techniques (UV-visible, IR, NMR, and mass), thermal analysis (TGA and DSC) measurements, and SEM. Also, the mode of complexation is determined using IR and NMR spectroscopy. The scanning electron micrographs show that the hydrogel has a great ability to recover the metal ions in the following order: Hg2+ > Cd2+ > Pb2+ > Cu2+. TGA thermograms are used to investigate the mechanism of thermal decomposition. (C) 2000 John Wiley & Sons, Inc. [References: 10]
机译:通过辐射聚合制备了一种新型的含硫水凝胶,并讨论了其在回收Hg2 +,Pb2 +,Cd2 +和Cu2 +离子中的应用。通过使用不同的光谱技术(紫外可见,IR,NMR和质谱),热分析(TGA和DSC)测量和SEM分离并表征金属水凝胶配合物。同样,使用IR和NMR光谱确定络合模式。扫描电子显微镜照片显示,水凝胶具有按以下顺序回收金属离子的强大能力:Hg2 +> Cd2 +> Pb2 +> Cu2 +。 TGA热分析图用于研究热分解的机理。 (C)2000 John Wiley&Sons,Inc. [参考:10]

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