Complexes of 1-vinylazoles with transition metals in radical polymerization

Danilovtseva EN.; Skushnikova AI.; Svyatkina LI.; Annenkov VV.

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Complexes of 1-vinylazoles with transition metals in radical polymerization

机译：自由基聚合中1-乙烯基唑与过渡金属的配合物

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Radical polymerization of the complexes of 1-vinylimidazole, 1-vinylbenzimidazole, and 1-vinylbenztriazole with MnCl2, NiCl2, and ZnCl2, was investigated. It was found that the polymerization is accompanied by spontaneous polymerization in the case of MnCl2 and ZnCl2, inhibition by coordination of macroradicals with Ni2+ ions, and a gel effect by crosslinking of the formed polymer during the complexing with Zn2+. (C) 2000 John Wiley & Sons, Inc. [References: 15]

机译：研究了1-乙烯基咪唑，1-乙烯基苯并咪唑和1-乙烯基苯并三唑与MnCl2，NiCl2和ZnCl2的自由基聚合反应。发现在MnCl 2和ZnCl 2的情况下，聚合伴随有自发聚合，通过大自由基与Ni 2+离子的配位而被抑制，并且在与Zn 2+络合期间通过形成的聚合物的交联而产生凝胶效应。（C）2000 John Wiley＆Sons，Inc. [参考：15]

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《Journal of Applied Polymer Science》 |2000年第1期|共8页
作者
Danilovtseva EN.; Skushnikova AI.; Svyatkina LI.; Annenkov VV.;
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正文语种 eng
中图分类高分子化学（高聚物）;高分子化合物产品;有机化学;
关键词
Polymerization; Azole; Vinyl; Metal; Complex; Dichloride;

机译：聚合;唑;乙烯基;金属;络合物;二氯化物;

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专利

1. Complexes of 1-vinylazoles with transition metals in radical polymerization [J] . Danilovtseva EN., Skushnikova AI., Svyatkina LI., Journal of Applied Polymer Science . 2000,第1期

机译：自由基聚合中1-乙烯基唑与过渡金属的配合物
2. Catalytic activities of ruthenium(II) complexes in transition-metal-mediated living radical polymerization: Polymerization, model reaction, and cyclic voltammetry [J] . Ando T., Sawamoto M., Kamigaito M. Macromolecules . 2000,第16期

机译：钌（II）配合物在过渡金属介导的活性自由基聚合中的催化活性：聚合，模型反应和循环伏安法
3. Controlled radical polymerizations mediated by one-electron atom-transfer chemistry of transition-metal complexes: electrochemistry and combinatorial approaches [J] . Bruce M. Novak, Christopher Goh, Young-Je Kwark Polymer Preprints . 1999,第2期

机译：过渡金属配合物的单电子原子转移化学介导的受控自由基聚合：电化学和组合方法
4. Living Radical Polymerizations Mediated by Metallo-Radical and Organo-Transition Metal Complexes [C] . Bradford B. Wayland, Xuefeng Fu, Chi-How Peng, American Chemical Society . 2006

机译：由金属 - 自由基和有机过渡金属配合物介导的活性自由基聚合
5. Part I. Study of transition metal complexes with 3-nitrogen donor ligands. Part II. Applications of cobalt metalloradicals in controlled radical polymerization. [D] . Lu, Zhi. 2004

机译：第一部分：具有3-氮供体配体的过渡金属配合物的研究。第二部分钴金属钴在受控自由基聚合中的应用。
6. Transition Metal Complexes and Radical Anion Salts of 110-Phenanthroline Derivatives Annulated with a 125-Tiadiazole and 125-Tiadiazole 11-Dioxide Moiety: Multidimensional Crystal Structures and Various Magnetic Properties [O] . Yoshiaki Shuku, Kunio Awaga 2014

机译：与125-噻二唑和125-噻二唑11-二氧化物部分环合的110-菲咯啉衍生物的过渡金属配合物和自由基阴离子盐：多维晶体结构和各种磁性
7. First-row transition-metal complexes based on a carboxylate polychlorotriphenylmethyl radical: Trends in metal-radical exchange interactions [O] . Maspoch Daniel, Domingo Neus, Ruiz Molina Daniel, 2017

机译：基于羧酸根的聚氯三苯基甲基自由基的第一行过渡金属配合物：金属-自由基交换相互作用的趋势
8. Living/Controlled Radical Polymerization. Transition-Metal-Catalyzed AtomTransfer Radical Polymerization in the Presence of a Conventional Radical Initiator [R] . Wang, J. S., Matyjaszewski, K. 1995

机译：活性/可控自由基聚合。在常规自由基引发剂存在下的过渡金属催化的原子转移自由基聚合

Complexes of 1-vinylazoles with transition metals in radical polymerization

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