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Toughening of PP/EPDM blend by compatibilization

机译:通过相容性增韧PP / EPDM共混物

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摘要

To improve the mechanical properties of blends of polypropylene (PP) and terpolymer of ethylene-propylene-diene, (EPDM), a triblock copolymer, (PP-g-MAH)-co-[PA-6,6]-co-(EPDM-g-MAH), was synthesized by coupling reaction of maleic anhydride (MAH)-grafted PP (PP-g-MAH), EPDM-g-MAH, and PA-6,6. The newly prepared block copolymer brought about a physical interlocking between the blend components, and imparted a compatibilizing effect to the blends. Introducing the block copolymer to the blends up to 5 wt % lead to formation of a beta-form crystal. The wide-angle X-ray diffractograms measured in the region of 2 theta between 10 degrees and 50 degrees ascertained that incorporating the block copolymer gave a new peak at 2 theta = 15.8 degrees. The new peak was assigned to the (300) plane spacings of the beta-hexagonal crystal structure. In addition, the block copolymer notably improved the low-temperature impact property of the PP/EPDM blends. The optimum usage level of the compatibilizer proved to be 0.5 wt %. (C) 2000 John Wiley & Sons, Inc. [References: 18]
机译:为了改善聚丙烯(PP)和乙烯-丙烯-二烯(EPDM)三元共聚物的共混物的机械性能,三嵌段共聚物(PP-g-MAH)-共-[PA-6,6]-共-( EPDM-g-MAH)是通过马来酸酐(MAH)接枝的PP(PP-g-MAH),EPDM-g-MAH和PA-6,6的偶联反应合成的。新制备的嵌段共聚物在共混物组分之间实现了物理互锁,并赋予了共混物以增容作用。将嵌段共聚物引入混合物中至多5重量%导致形成β-型晶体。在10度至50度之间的2θ区域中测量的广角X射线衍射图确定,掺入嵌段共聚物在2θ= 15.8度处给出新的峰。新峰分配给β-六方晶体结构的(300)平面间距。另外,嵌段共聚物显着改善了PP / EPDM共混物的低温冲击性能。增容剂的最佳用量证明为0.5重量%。 (C)2000 John Wiley&Sons,Inc. [参考:18]

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