Synthesis ,X-ray Structure,and Polymerization of 1-Vinyl-3cyanomethylimidazolium Chloride

Sergey E.Evsyukov; ranck Gautheron; H.Wolfgang Hoffken; Karlheinz Bohn

首页> 外文期刊>Journal of Applied Polymer Science >Synthesis ,X-ray Structure,and Polymerization of 1-Vinyl-3cyanomethylimidazolium Chloride

【24h】

Synthesis ,X-ray Structure,and Polymerization of 1-Vinyl-3cyanomethylimidazolium Chloride

机译：1-乙烯基-3氰基甲基咪唑鎓氯化物的合成，X射线结构及聚合

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A new monomer ,1-vinyl-3-cyanomethylimidazolium chloride(1 )was synthesized via quaternization of 1-vinylimidazole with chloroacetonitrile.Th monomer was characterized using ~1H-and ~(13)C-NMR as well as Raman spectroscopic techniques;its crystal structure was studied by means of X-ray analysis.The radical polymerization of 1 in aqueous solution brought about the formation of a polyelectrolyte that retains cyano groups intact and possesses film-forming properties.The structure of the polymer was characterized by NMR and Raman spectroscopy,The high viscosity of aqueous solutions and chemical structure of the polymer obtained suggest its possible applications as a thickener and/or detergent additive.

机译：通过1-乙烯基咪唑与氯乙腈的季铵化反应合成了一种新的1-乙烯基-3-氰基甲基咪唑鎓氯化物（1）。用〜1H-和〜（13）C-NMR以及拉曼光谱技术对其进行了表征。通过X射线分析研究其晶体结构。水溶液中1的自由基聚合导致形成了保留氰基完整并具有成膜性能的聚电解质。该聚合物的结构通过NMR和Raman表征光谱学，水溶液的高粘度和所得聚合物的化学结构表明其可能用作增稠剂和/或去污剂添加剂。

著录项

来源
《Journal of Applied Polymer Science》 |2001年第2期|共11页
作者
Sergey E.Evsyukov; ranck Gautheron; H.Wolfgang Hoffken; Karlheinz Bohn;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类高分子化学（高聚物）;高分子化合物产品;有机化学;
关键词
1-vinyl-3-cyanomethylimidazolium chloride; molecular structure; radical polymerization;

机译：1-乙烯基-3-氰基甲基咪唑氯化物;分子结构;自由基聚合;

相似文献

外文文献
中文文献
专利

1. Synthesis ,X-ray Structure,and Polymerization of 1-Vinyl-3cyanomethylimidazolium Chloride [J] . Sergey E.Evsyukov, ranck Gautheron, H.Wolfgang Hoffken, Journal of Applied Polymer Science . 2001,第2期

机译：1-乙烯基-3氰基甲基咪唑鎓氯化物的合成，X射线结构及聚合
2. A chloride-bridged chain polymer: synthesis and X-ray structure of [GdCl(mu-Cl)(2)(H2O)(2)CH3CN] [J] . Rudd MD., Alcock NW., Willey GR. Inorganica Chimica Acta . 2003,第0期

机译：氯桥链聚合物：[GdCl（mu-Cl）（2）（H2O）（2）CH3CN]的合成及X射线结构
3. Synthesis of chiral organotin reagents: synthesis of enantiomerically enriched bicyclo[2.2.1]hept-2-yl tin hydrides from camphor. X-Ray crystal structures of (dimethyl)[(1R,2S,4R)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl]tin chloride and methyl(phenyl)bis[(1R,2S,4R)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl]stannane [J] . Madeleine Helliwell Eric J. Thomas and Linda A. Townsend Journal of the Chemical Society, Perkin Transactions 1 . 2002,第10期

机译：手性有机锡试剂的合成：从樟脑合成对映异构体富集的双环[2.2.1]庚-2-基氢化锡。（二甲基）[（1R，2S，4R）-1,7,7-三甲基双环[2.2.1]庚-2-基]氯化锡和甲基（苯基）双[（1R，2S， 4R）-1,7,7-三甲基双环[2.2.1]庚-2-基]锡烷
4. Gold Nanoparrticles on Polymeric Micro Beads: A One-Pot Synthesis and Characterization by X-Ray Absorption Near Edge Structure (XANES) Spectroscopy [C] . C.S.S.R. Kumar, M. Aghasyan, H. Modrow International Conference on Materials for Advanced Technologies . 2005

机译：聚合物微珠粒上的金纳米圆锥：通过边缘结构（XANES）光谱附近的X射线吸收的单罐合成和表征
5. Structure-reactivity investigations of ethylene polymerization and copolymerization using zwitterionic nickel and palladium complexes, and copolymerization of carbon dioxede and epoxides using salen chromium chloride complexes. [D] . Fang, Cindy Ching. 2003

机译：使用两性离子镍和钯配合物进行乙烯聚合和共聚反应，以及使用Salen氯化铬配合物进行二氧化碳和环氧化合物的共聚反应的结构反应性研究。
6. Polymers of ε-Caprolactone Using New Copper(II) and Zinc(II) Complexes as Initiators: Synthesis Characterization and X-Ray Crystal Structures [O] . Andrés F. Posada, Mario A. Macías, Santiago Movilla, 2018

机译：使用新型铜（II）和锌（II）配合物作为引发剂的ε-己内酯聚合物：合成表征和X射线晶体结构
7. Distortion Isomerism of Cu(II) Chloride Adducts with Bis(2-benzimidazolyl)ethane. Synthesis, Characterization, X-ray Structures and Spectroscopy of Four Different Isomers [O] . 2007

机译：氯化铜（II）加合物与双（2-苯并咪唑基）乙烷的扭曲异构现象。四种不同异构体的合成，表征，X射线结构和光谱
8. Synthesis and Characterization of Trimethylsilylphosphide Derivatives ofDineopentylindium Chloride. X-ray Crystal Structures of (ME(Me3CCH2)InP(SiMe3)2)2, (Me3CCH2)2 InP(SiMe3)2In(CH2CMe3)2Cl, and ((Me3CCH2)2 InP(SiMe3)2In(CH2CMe3)2PH(SiMe3)) [R] . Wells, R. L., McPhail, A. T., Self, M. F. 1993

机译：二新戊基氯化铟三甲基甲硅烷基磷化物衍生物的合成与表征。（mE（me3CCH2）Inp（sime3）2）2，（me3CCH2）2Inp（sime3）2In（CH2Cme3）2Cl和（（me3CCH2）2Inp（sime3）2In（CH2Cme3）2pH（sime3）的X射线晶体结构））

Synthesis ,X-ray Structure,and Polymerization of 1-Vinyl-3cyanomethylimidazolium Chloride

摘要

著录项

相似文献

相关主题

期刊订阅