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Synthesis of Amphiphilic Microspheres by Suspension Copolymerization of Styrene and Poly(ethylene oxide) Macromonomer

机译:苯乙烯与聚环氧乙烷大分子单体的悬浮共聚合成两亲性微球

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摘要

Amphiphilic microspheres,ranging in size from 3 to 35#mu#m,were prepared by suspension copolymerization of styrene with poly(ethylene oxide) vinylbenzyl (PEO-VB) macromonomer by changing polymerization conditions.It was found that an increase in the amount of dispersant and the PEO-VB concentration resulted in decreases of the size and size distribution of amphiphilic microspheres.The morphology,size,and size distribution of amphiphilic microspheres were characterized by scanning electron microscopy.The structure of copolymer was confirmed by infrared spectroscopy,differential scanning calorimetry,elemental analysis,and X-ray photoelectron spectroscopy.The content of the hydroxyl groups localized in the microspheres ranged from.
机译:通过改变聚合条件,通过苯乙烯与聚环氧乙烷乙烯基苄基(PEO-VB)大单体的悬浮共聚反应制备了尺寸为3〜35#μm的两亲性微球。分散剂和PEO-VB浓度导致两亲微球的尺寸和尺寸分布减小。通过扫描电子显微镜表征两亲微球的形貌,尺寸和尺寸分布。通过红外光谱,差示扫描确认共聚物的结构量热法,元素分析和X射线光电子能谱。位于微球中的羟基含量范围不等。

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