首页> 外文期刊>Journal of Applied Polymer Science >Polyether-segmented nylon hemodialysis membrane. VII. Studies on surface structures of various poly(ethylene oxide)-segmented nylon membranes
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Polyether-segmented nylon hemodialysis membrane. VII. Studies on surface structures of various poly(ethylene oxide)-segmented nylon membranes

机译:聚醚分段尼龙血液透析膜。七。各种聚环氧乙烷细分尼龙膜的表面结构研究

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The relationships of the surface morphologies to the surface chemical compositions in poly(ethylene oxide)-segmented nylon (PEO-Ny) membranes prepared by the phase-inversion method were studied using scanning electron microscopy (SEM), electron spectroscopy for chemical analysis (ESCA), and static secondary ion mass spectrometry (SSIMS). The PEG-Ny's used were high semicrystalline PEO-segmented polyiminosebacoyliminohexamethylene (PEO-Ny610), low semicrystalline PEO-segmented poly(iminosebacoylimino-m-xylylene) (PEO-NyM10), and amorphous PEO-segmented poly(iminoisophthaloyliminomethylene-1,3-cyclohexylenemethylene) (PEO-NyBI). SEM observation showed that the surfaces of the PEO-Ny610 and PEO-NyM10 membranes were composed of crystalline spherulite and that the PEO-NyBI membrane surface had a nodular structure. ESCA analysis exhibited the enrichment of the PEO segment at the surfaces of the PEO-Ny610 and PEO-NyM10 membranes. On the other hand, the enrichment of the Ny segment was observed in the case of the PEO-NyBI membrane. SSIMS analysis revealed that the outermost surfaces of the PEO-Ny membranes except the PEO-NyBI membrane were almost covered with the PEO segment. (C) 2000 John Wiley & Sons, Inc. [References: 20]
机译:利用扫描电子显微镜(SEM),化学电子学(ESCA)研究了通过相转化法制备的聚(环氧乙烷)-分割尼龙(PEO-Ny)膜的表面形态与表面化学组成的关系。 )和静态二次离子质谱(SSIMS)。所使用的PEG-Ny是高半结晶PEO分段的聚亚氨基葡糖基亚氨基六亚甲基(PEO-Ny610),低半结晶PEO分段的聚(亚氨基葡糖酰亚胺-间二甲苯)(PEO-NyM10)和无定形PEO分段的聚(亚氨基间苯二甲酰亚甲基-1,3-环己烯基亚甲基)(PEO-NyBI)。 SEM观察表明,PEO-Ny610和PEO-NyM10膜的表面由球晶组成,PEO-NyBI膜的表面呈球状结构。 ESCA分析显示,PEO-Ny610和PEO-NyM10膜表面的PEO链段富集。另一方面,在PEO-NyBI膜的情况下,观察到了Ny片段的富集。 SSIMS分析显示,除了PEO-NyBI膜之外,PEO-Ny膜的最外表面几乎被PEO链段覆盖。 (C)2000 John Wiley&Sons,Inc. [参考:20]

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