Different Surface-Substituted Polyorganosiloxane Microgels as Support Materials for MAO-Type Cocatalysts

Roland Schmidt; Helmut G. Alt; Jochen Ebenhoch

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Different Surface-Substituted Polyorganosiloxane Microgels as Support Materials for MAO-Type Cocatalysts

机译：不同的表面取代聚有机硅氧烷微凝胶作为MAO型助催化剂的载体材料

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Twenty-five different functionalized and nonfunctionalized polyorganosiloxane microgels were applied as support materials for methylalumoxane (MAO)-type compounds to give various heterogeneous cocatalysts which are able to activate metallocene complexes like Cp_2ZrCl_2 for ethene polymerization. The functionalization of the microgels has a strong influence on the properties of the catalysts and the produced polyethenes.

机译：将二十五个不同的官能化和非官能化的聚有机硅氧烷微凝胶用作甲基铝氧烷（MAO）型化合物的载体材料，得到各种能够活化茂金属络合物（如Cp_2ZrCl_2）用于乙烯聚合的多相助催化剂。微凝胶的功能化对催化剂和所产生的聚乙烯的性能有很大的影响。

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《Journal of Applied Polymer Science》 |2001年第2期|共5页
作者
Roland Schmidt; Helmut G. Alt; Jochen Ebenhoch;
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正文语种 eng
中图分类高分子化学（高聚物）;高分子化合物产品;有机化学;
关键词
polyorganosiloxane microgels; metallocene catalysts; support; heterogeneous polymerization; polyethene;

机译：聚有机硅氧烷微凝胶;茂金属催化剂;载体;非均相聚合;聚乙烯;

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1. Different Surface-Substituted Polyorganosiloxane Microgels as Support Materials for MAO-Type Cocatalysts [J] . Roland Schmidt, Helmut G. Alt, Jochen Ebenhoch Journal of Applied Polymer Science . 2001,第2期

机译：不同的表面取代聚有机硅氧烷微凝胶作为MAO型助催化剂的载体材料
2. Heterogeneous Polymerization of Ethene with Metallocene Catalysts. A Comparison of Poly(organosiloxane) Microgels and Silica as Support Materials for MAO-Type Cocatalysts [J] . ROLAND SCHMIDT, HELMUT G.ALT, JOCHEN EBENHOCH Journal of Applied Polymer Science . 2001,第4期

机译：乙烯与茂金属催化剂的非均相聚合。聚（有机硅氧烷）微凝胶和二氧化硅作为MAO型助催化剂载体材料的比较
3. Microgels as new support materials for heterogeneous cocatalysts in ethylene polymerization reactions [J] . Helldorfer M., Alt HG., Ebenhoch J. Journal of Applied Polymer Science . 2002,第12期

机译：微凝胶作为乙烯聚合反应中非均相助催化剂的新型载体材料
4. THE INFLUENES OF TEMPERATURE AND COCATALYST ON PROPYLENE POLYMERIZATION WITH A MgCl2-SUPPORTED TiCi4 CATALYST SYSTEM [C] . . -1

机译：MgCl2支撑的TiCi4催化剂体系中温度和助催化剂对丙烯聚合反应的影响
5. Microgels at the Oil-water Interfaces: From Fundamental Physics to Functional Materials. [D] . Li, Zifu. 2012

机译：油-水界面处的微凝胶：从基础物理到功能材料。
6. Microfluidic Fabrication of Click Chemistry-Mediated Hyaluronic Acid Microgels: A Bottom-Up Material Guide to Tailor a Microgel’s Physicochemical and Mechanical Properties [O] . Thomas Heida, Oliver Otto, Doreen Biedenweg, 2020

机译：单击化学介导的透明质酸微凝胶的微流体制造：自下而上的材料指南以定制微凝胶的物理化学和机械性能
7. Biomimetic polyorganosiloxanes:Model compounds for new materials [O] . Kociok-Kohn Gabriele, Mahon Mary F., Molloy Kieran C., 2014

机译：仿生聚有机硅氧烷：新材料的模型化合物
8. Support Materials for Language and System Support for Concurrent Programming [R] . Feldman, M. B., Ford, G. 1990

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Different Surface-Substituted Polyorganosiloxane Microgels as Support Materials for MAO-Type Cocatalysts

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