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首页> 外文期刊>Journal of Applied Polymer Science >Synthesis of New Electron Transfer Polymers for the Reduction of Dissolved Oxygen in Water
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Synthesis of New Electron Transfer Polymers for the Reduction of Dissolved Oxygen in Water

机译:用于减少水中溶解氧的新型电子转移聚合物的合成

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摘要

Polymers based upon hydroquinone-quinone redox system were prepared by the addition of hydroquinone and methylhydroquinone to polymerization of monomers containing the redox system. In the last case, composition and structure of macromolecules are known with increased certainty and so, they are readily characterized. For the first time, preparation and polymerization of monomers are realized with good yields. By using these macromolecules to remove oxygen fro water, it was established that redoxite properties of Electron Transfer Polymers (ETP) have been closely related to the number of redox functions on the polymer matrix.
机译:通过将对苯二酚和甲基对苯二酚添加到含有氧化还原体系的单体的聚合反应中,制得基于对苯二酚-醌氧化还原体系的聚合物。在最后一种情况下,大分子的组成和结构的确定性提高了,因此很容易对其进行表征。首次以高收率实现单体的制备和聚合。通过使用这些大分子去除水中的氧气,可以确定电子转移聚合物(ETP)的氧化还原性质与聚合物基质上的氧化还原功能数量密切相关。

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