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Study of Adsorption of Nonionic Surfactants at the Liquid-Soild Interface by FTIR/CIR

机译:FTIR / CIR研究液体表面上非离子表面活性剂的吸附

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Fourier transform infrared spectrosocpy (FTIR), using the attenuated total reflectance (ATR) method, can be used to characterize the interface of a system. We investigated the adsorption at the liquid-solid interface of nonionic surfactant aqueous solutions with or without a hydrotropic agent. We studied monofunctional diblock copolymers of poly(ethylene oxide-propylene oxide) (PEO-PPO) as nonionic sufactants and sodium p-toluenesulfonate (NaPTS) as hydrotropic agent. The samples were analyzed by FTIR technique using the circular internal reflectance (CIR) accessory, which confirmed that the hydrotrope shifts the surfactant from the liquid-solid interface.
机译:使用衰减全反射率(ATR)方法的傅立叶变换红外光谱(FTIR)可用于表征系统的界面。我们研究了有或没有水溶助剂的非离子表面活性剂水溶液在液-固界面处的吸附。我们研究了聚(环氧乙烷-环氧丙烷)(PEO-PPO)作为非离子表面活性剂和对甲苯磺酸钠(NaPTS)作为水溶助剂的单官能二嵌段共聚物。使用圆内反射率(CIR)附件通过FTIR技术对样品进行分析,这证实了水溶助长剂将表面活性剂从液-固界面移开。

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