Unsaturated Polyester Resins Cure: Kinetic, Rheologic, and Mechnical-Dynamical Analysis. I. Cure Kinetics by DSC and TSR

J.L.VILAS; J.M.LAZA; M.T.GARAY; M.RODRIGUEZ; L.M.LEON

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Unsaturated Polyester Resins Cure: Kinetic, Rheologic, and Mechnical-Dynamical Analysis. I. Cure Kinetics by DSC and TSR

机译：不饱和聚酯树脂的固化：动力学，流变和机械动力学分析。 I. DSC和TSR的固化动力学

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The curing reaction of a polyester resin, using methyl ethyl ketone peroxide and cobalt octoate as promoter, has been studied buy differential scanning calorimetry and therma lscanning rheometry under isothermal conditions. All kinetic paraemters of the curing reaction, including the reaction order, activation energy, and the rate constant, were calculated and reported using different empirical relationships. The gel time, which is defined by several criteria, was used to determine the apparent activation energy of the process.

机译：用差示扫描量热法和热扫描流变法在等温条件下研究了以过氧化甲乙酮和辛酸钴为促进剂的聚酯树脂的固化反应。使用不同的经验关系来计算和报告固化反应的所有动力学参数，包括反应顺序，活化能和速率常数。由几个标准定义的胶凝时间用于确定该过程的表观活化能。

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《Journal of Applied Polymer Science》 |2001年第3期|共11页
作者
J.L.VILAS; J.M.LAZA; M.T.GARAY; M.RODRIGUEZ; L.M.LEON;
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正文语种 eng
中图分类高分子化学（高聚物）;高分子化合物产品;有机化学;
关键词
unsaturated polyester resin; curing reaction; gel time; DSC; thermla scanning rheometry;

机译：不饱和聚酯树脂固化反应凝胶时间DSC热扫描流变仪;

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1. Unsaturated Polyester Resins Cure: Kinetic, Rheologic, and Mechnical-Dynamical Analysis. I. Cure Kinetics by DSC and TSR [J] . J.L.VILAS, J.M.LAZA, M.T.GARAY, Journal of Applied Polymer Science . 2001,第3期

机译：不饱和聚酯树脂的固化：动力学，流变和机械动力学分析。 I. DSC和TSR的固化动力学
2. Unsaturated polyester resins cure: kinetic,Rheologic,and Mechanical Dynamical Analysis.II.The Glass Transition in the Mechanical Dynamical Spectrum of Polyester Networks [J] . J.L.Vilas, J.M.Laza, M.T.Garay, Journal of Polymer Science, Part B. Polymer Physics . 2001,第1期

机译：不饱和聚酯树脂的固化：动力学，流变学和机械动力学分析II。聚酯网络机械动力学光谱中的玻璃化转变
3. Kinetic analysis of two DSC peaks in the curing of an unsaturated polyester resin catalyzed with methylethyl ketone peroxide and cobalt octoate [J] . Martin JL Polymer engineering and science . 2007,第1期

机译：过氧化甲乙酮和辛酸钴催化不饱和聚酯树脂固化中两个DSC峰的动力学分析
4. KINETIC ANALYSIS OF DIFFERENT PEROXIDE INITIATORS ON THE CURE BEHAVIOR OF BIO-BASED AND RECYCLED UNSATURATED POLYESTER ENVIREZ RESINS [C] . Shatori S. Meadows, Mahesh V. Hosur, Alfred Tcherbi-Narteh Composites and Advanced Materials Expo . 2015

机译：不同过氧化物引发剂对生物基和再生不饱和聚酯envirez树脂的固化行为的动力学分析
5. Integrated analysis of low profile unsaturated polyester and vinylester resins cured at low temperatures. [D] . Cao, Xia. 2002

机译：对低温固化的低型不饱和聚酯和乙烯基酯树脂的综合分析。
6. Comparative Effect of Self- or Dual-Curing on Polymerization Kinetics and Mechanical Properties in a Novel Dental-Resin-Based Composite with Alkaline Filler. Running Title: Resin-Composites with Alkaline Fillers [O] . Nicoleta Ilie 2018

机译：自固化或双固化对新型含碱性填料的牙科树脂基复合材料的聚合动力学和力学性能的比较影响。连续标题：含碱性填料的树脂复合材料
7. Influence of glass and sisal fibers on the cure kinetics of unsaturated polyester resin [O] . Vinicius Pistor, Silvia Simone da Silva dos Santos Soares, Heitor Luiz Ornaghi Júnior, 2012

机译：玻璃和剑麻纤维对不饱和聚酯树脂固化动力学的影响
8. Some Experiments on the Cure of an Unsaturated Polyester System. Part II. Measurement of Volume Resistivity, Barcol Hardness and Acetone Extraction in the Advanced Stages of the Curing Reaction [R] . Judd, N. C. W. 1966

机译：不饱和聚酯体系固化的几点实验。第二部分。固化反应高级阶段体积电阻率，巴氏硬度和丙酮萃取的测定

Unsaturated Polyester Resins Cure: Kinetic, Rheologic, and Mechnical-Dynamical Analysis. I. Cure Kinetics by DSC and TSR

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