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Use of Silanes and Copolyemers as Adhesion promoters in Glass Fiber/Polyethylene Coposites

机译:硅烷和共聚物在玻璃纤维/聚乙烯复合材料中作为粘合促进剂的用途

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摘要

Two organofunctional silanes and three functionalized copolymers were used as adhesion promoters in glass fiber/polyethylene-reinforced composites. The performance of the coupling agents was investigated by mechanical property measure-ments, scanning electron microscopy, and dynamic mechanical analysis. Coupling achieved with the poly(ethylene-g-maleic anhydride) copolymer proved to be the most successful compared with the other copolymers (ethylene/vinyl alcohol, ethylene/acrylic acid) and silane agents (y~methacryloxypropyltrimethoXy, cationic styryl). The com-bined coupling performance of the silanes and copolymers examined in this study appears to be controlled by the coupling performance of the copolymer. Effective coupling was reflected in increased mechanical properties. Increased fiber/matrix ad-hesion is not always associated with effective coupling because structural changes occurring at the interface region can result in a deterioration of the material property.
机译:两种有机官能硅烷和三种官能化共聚物用作玻璃纤维/聚乙烯增强复合材料的粘合促进剂。通过机械性能测量,扫描电子显微镜和动态力学分析研究了偶联剂的性能。与其他共聚物(乙烯/乙烯醇,乙烯/丙烯酸)和硅烷试剂(γ-甲基丙烯酰氧基丙基三甲氧基,阳离子苯乙烯基)相比,用聚(乙烯-g-马来酸酐)共聚物实现的偶联被证明是最成功的。本研究中研究的硅烷和共聚物的联合偶联性能似乎受共聚物的偶联性能控制。有效的耦合反映在增加的机械性能中。增加的纤维/基体粘合力并不总是与有效的耦合有关,因为在界面区域发生的结构变化可能导致材料性能下降。

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