Synthesis of Monodisperse Poly(butyl acrylate) Initiated by SmMe(C_5Me_5)_2 (THF) and Its Adhesive Properties After Crosslinking by Electron-Beam Irradiation

YOSHIHIDE KAWAGUCHI; HAJIME YASUDA

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Synthesis of Monodisperse Poly(butyl acrylate) Initiated by SmMe(C_5Me_5)_2 (THF) and Its Adhesive Properties After Crosslinking by Electron-Beam Irradiation

机译：SmMe（C_5Me_5）_2（THF）引发的单分散聚丙烯酸丁酯的合成及其电子束辐照后的粘合性能

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Polymerization reactions of butyl acrylate (BuA) were carried out using an organosamarium complex, SmMe(C_5Me_5)_2 (THF), as an initiator. Polymerization proceeds quantiatively to give high number-average molecular mass polymers (M_n > 200, 000) and narorow molecular weight distributions (M_w/.M_n < 1.07). Irradiation of the resuting poly(BuA) with an electron beam (EB) gave crosslinked poly(BuA). Improved viscoelastic and adhesive properties of these polymers were useful for high-temperature applications.

机译：使用有机sa络合物SmMe（C_5Me_5）_2（THF）作为引发剂进行丙烯酸丁酯（BuA）的聚合反应。聚合定量进行，得到高数均分子量的聚合物（M_n> 200，000）和自然分子量分布（M_w / .M_n <1.07）。用电子束（EB）照射重排的聚（BuA），得到交联的聚（BuA）。这些聚合物的改进的粘弹性和粘合性能可用于高温应用。

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来源
《Journal of Applied Polymer Science》 |2001年第3期|共6页
作者
YOSHIHIDE KAWAGUCHI; HAJIME YASUDA;
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正文语种 eng
中图分类高分子化学（高聚物）;高分子化合物产品;有机化学;
关键词
poly(butyl acrylate); adhesive property; electron-beam irradiation; SmMe(C_5Me_5)_2(THF);

机译：聚丙烯酸丁酯;粘合性能;电子束辐照;SmMe（C_5Me_5）_2（THF）;

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1. Synthesis of Monodisperse Poly(butyl acrylate) Initiated by SmMe(C_5Me_5)_2 (THF) and Its Adhesive Properties After Crosslinking by Electron-Beam Irradiation [J] . YOSHIHIDE KAWAGUCHI, HAJIME YASUDA Journal of Applied Polymer Science . 2001,第3期

机译：SmMe（C_5Me_5）_2（THF）引发的单分散聚丙烯酸丁酯的合成及其电子束辐照后的粘合性能
2. Synthesis of Poly(e-caprolactone)-block-Poly(n-butyl acrylate) by the Combination of Ring-Opening Polymerization and Atom Transfer Radical Polymerization with Ti[OCH2CCl3]4 as a Difunctional Initiator. II.Synthesis and Characterization of Poly(e-caprolactone)-block-Poly(n-butyl acrylate) Copolymers [J] . Peichun Li, Zhean Xia, Amar Zerroukhi, Journal of Applied Polymer Science . 2010,第4期

机译：Ti [OCH2CCl3] 4作为双官能团引发剂，通过开环聚合和原子转移自由基聚合相结合，合成聚（ε-己内酯）嵌段聚（丙烯酸正丁酯）。 II。聚（ε-己内酯）-嵌段-聚（丙烯酸正丁酯）共聚物的合成与表征
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Synthesis of Monodisperse Poly(butyl acrylate) Initiated by SmMe(C_5Me_5)_2 (THF) and Its Adhesive Properties After Crosslinking by Electron-Beam Irradiation

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