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Junction Properties of Metal/Polypyrrole Schottky Barriers

机译:金属/聚吡咯肖特基势垒的结性质

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Schottky barriers of the type Au/polypyrrole/Al (or In) were made in sand- wichconfiguration. The conductivity ofpolypyrrole was tuned to be on the order of 10~(-3) ohm~(-1)cm~(-1) by its electrodeposition from a novel ambient temperature ternary eutectic melt consisting of acetamide, urea, and ammonium nitrate. The rectification charac-teristics were obtained from the currept-voltage and capacitance-voltage measure-ments at room temperature. The analysis of data using thermionic emission theory gave improved values for the junction parameters of ideality factor, reverse saturation current, rectification ratio, and barrier potential when compared to the previously reported values for this polymer. Between Al and fu metals used Ior the junction formation, the diode formed with Al metal is found to show better performance. The energy gap and work function orpolypyrrole were also estimated.
机译:Au /聚吡咯/ Al(或In)类型的肖特基势垒采用三明治结构制成。聚吡咯的电导率是由一种新型的由乙酰胺,尿素和硝酸铵组成的三元环境共熔熔体进行电沉积而调节的,其电导率约为10〜(-3)ohm〜(-1)cm〜(-1)。从室温下的电流电压和电容电压测量值获得整流特性。当与该聚合物先前报道的值相比时,使用热电子发射理论的数据分析给出了理想因子,反向饱和电流,整流比和势垒电势的结参数的改进值。在铝和付金属之间或结形成中,发现由铝金属形成的二极管表现出更好的性能。还估计了能隙和功函数或聚吡咯。

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