Radical Polymerization of N-[(1-n-butoxycarbyl) ethyl] ethymaleimide

Jiaoyan Ai; Pengsheng Liu; Hongyan Tan; Rengui Lei

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Radical Polymerization of N-[(1-n-butoxycarbyl) ethyl] ethymaleimide

机译：N-[（1-正丁氧基羰基）乙基]乙基马来酰亚胺的自由基聚合

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Radical Polymerization of N-[(1-n-butoxycarbyl) ethyl] ethymaleimide (PBAM) was syntheSized by solution polymerization with 2,2'-Azobis(isobutylronitrile)(AIBN) as radical initiator The resulting polymer(PBAM)was characterized by infrated spectroscopy(IR),themogravimetry (TG) ,and differential thermal analysis (DTA).The initial decomposition temperature of PBAM is 321.6 deg C ;the glass transition temperature of PBAM was 240.5 deg C.The dffects of solvent ,temperature,initiator concentration ([I]) ,and monomer concentration([BAM]) on polymerization were also discussed.The overall activation energy (E_a) of homopolymerization was determined(E=93.5kJ/mol) .It was revealed that the rate of polymerization (R_p) can be expressed as R_p x [I]~(0.58)[BAM] .

机译：以2,2'-偶氮二异丁腈（AIBN）为自由基引发剂，通过溶液聚合反应合成了N-[（1-正丁氧基羰基）乙基]乙基马来酰亚胺（PBAM）。红外光谱，热重分析和差热分析（DTA）.PBAM的初始分解温度为321.6摄氏度; PBAM的玻璃化转变温度为240.5摄氏度。溶剂，温度，引发剂浓度的影响[I]），还讨论了聚合反应中的单体浓度（[BAM]）。确定了均聚反应的总活化能（E_a）（E = 93.5kJ / mol）。揭示了聚合速率（R_p）可以表示为R_p x [I]〜（0.58）[BAM]。

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《Journal of Applied Polymer Science》 |2001年第2期|共4页
作者
Jiaoyan Ai; Pengsheng Liu; Hongyan Tan; Rengui Lei;
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正文语种 eng
中图分类高分子化学（高聚物）;高分子化合物产品;有机化学;
关键词
n-substituted maleimide; solution polymerization; n-(1-n-butoxycarbonyl)ethylmaleimide; homopolymerization; heat-resistant polymer;

机译：正取代马来酰亚胺;溶液聚合;正-[（1-正丁氧基羰基）乙基]马来酰亚胺;均聚;耐热聚合物;

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1. Radical Polymerization of N-[(1-n-butoxycarbyl) ethyl] ethymaleimide [J] . Jiaoyan Ai, Pengsheng Liu, Hongyan Tan, Journal of Applied Polymer Science . 2001,第2期

机译：N-[（1-正丁氧基羰基）乙基]乙基马来酰亚胺的自由基聚合
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Radical Polymerization of N-[(1-n-butoxycarbyl) ethyl] ethymaleimide

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