Free radical copolymerization of tert-butyl 3-isopropenylcumylperoxide with styrene and grafting of methyl methacrylate onto the copolymers

Guo XP.; Li ZA.; Du QG.; Yang YL.; Lin MD.

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Free radical copolymerization of tert-butyl 3-isopropenylcumylperoxide with styrene and grafting of methyl methacrylate onto the copolymers

机译：叔丁基3-异丙烯基枯基过氧化物与苯乙烯的自由基共聚反应和甲基丙烯酸甲酯的接枝反应

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Copolymers of tert-butyl-3-isopropenylcumylperoxide (D-120) with styrene (St) were prepared in bulk by using benzoyl peroxide as initiator at 80degreesC. The compositions of the copolymers were determined by H-1-NMR analysis. The reactivity ratios of D-120 and St were calculated by methods of Xelen-TudOs (K-T), Fineman-Ross (F-R), and Yezrielev-Brokhina-Roskin (YBR), respectively. Graft copolymers were obtained by grafting of methyl methacrylate (MMA) onto the copolymers during decomposition of peroxy bonds suspended in the backbone. (C) 2002 Wiley Periodicals, Inc. [References: 22]

机译：通过在80℃下使用过氧化苯甲酰作为引发剂，批量制备叔丁基-3-异丙烯基枯基过氧化物（D-120）与苯乙烯（St）的共聚物。共聚物的组成通过H-1-NMR分析确定。 D-120和St的反应率分别通过Xelen-TudOs（K-T），Fineman-Ross（F-R）和Yezrielev-Brokhina-Roskin（YBR）的方法计算。接枝共聚物是通过在骨架中悬浮的过氧键分解过程中将甲基丙烯酸甲酯（MMA）接枝到共聚物上而获得的。（C）2002 Wiley Periodicals，Inc. [参考：22]

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《Journal of Applied Polymer Science》 |2002年第12期|共9页
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Guo XP.; Li ZA.; Du QG.; Yang YL.; Lin MD.;
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正文语种 eng
中图分类高分子化学（高聚物）;高分子化合物产品;有机化学;
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1. Free radical copolymerization of tert-butyl 3-isopropenylcumylperoxide with styrene and grafting of methyl methacrylate onto the copolymers [J] . Guo XP., Li ZA., Du QG., Journal of Applied Polymer Science . 2002,第12期

机译：叔丁基3-异丙烯基枯基过氧化物与苯乙烯的自由基共聚反应和甲基丙烯酸甲酯的接枝反应
2. Preparation of a copolymer of methyl methacrylate with a new monomer, 2,2,6,6-tetramethyl-4-benzyloxyl-piperidinyl methacrylate, and its initiation of the graft copolymerization of styrene with a controlled radical mechanism [J] . Zhang HT., Guo ZR., Huang JL. Journal of Polymer Science, Part A. Polymer Chemistry . 2002,第24期

机译：甲基丙烯酸甲酯与新单体2,2,6,6-四甲基-4-苄氧基-甲基丙烯酸哌啶基酯的共聚物的制备，并通过受控的自由基机理引发苯乙烯的接枝共聚
3. Synthesis of styrene-methyl methacrylate graft and block-graft copolymers via combination of atom transfer radical polymerization and stable free radical polymerization [J] . Sebnem Inceoglu, Gurkan Hizal, Umit Tunca Designed Monomers and Polymers: An International Journal on Monomer and Macromolecular Synthesis . 2004,第1a2期

机译：原子转移自由基聚合与稳定自由基聚合相结合合成苯乙烯-甲基丙烯酸甲酯接枝和嵌段接枝共聚物
4. Graft Copolymerization of Methyl Methacrylate From Poly(Glycidyl Methacrylate-co-Styrene) Initiated by Cp2TiCl-Catalyzed Epoxide Radical Ring Opening [C] . Alexandru D. Asandei, Gobinda Saha PMSE Symposia . 2006

机译：CP2TICL催化环氧化物 - 开口引发的聚（甲基丙烯酸甲酯 - 共苯乙烯）从甲基丙烯酸甲酯的接枝共聚
5. Free radical (co)polymerization of methyl methacrylate and styrene in room temperature ionic liquids. [D] . Zhang, Hongwei. 2004

机译：甲基丙烯酸甲酯和苯乙烯在室温离子液体中的自由基（共）聚合。
6. A new initiating system based on (SiMes)Ru(PPh3)(Ind)Cl2 combined with azo-bis-isobutyronitrile in the polymerization and copolymerization of styrene and methyl methacrylate [O] . Abdullah M. Al-Majid, Waseem Sharaf Shamsan, Abdel-Basit Mohammed Al-Odayn, 2017

机译：SiMes Ru（PPh3）（Ind）Cl2与偶氮-双-异丁腈结合的新型引发体系用于苯乙烯和甲基丙烯酸甲酯的聚合和共聚
7. Free-Radical Copolymerization V. Rate Constants of Propagation and Termination for a Styrene/Methyl Methacrylate/Toluene System [O] . Takeshi Fukuda, Keiji Kubo, Yung-Dae Ma, 1987

机译：自由基共聚V.富含苯乙烯/甲基丙烯酸甲酯/甲苯系统的繁殖和终止的速率常数
8. Microstructure of Styrene Methyl Methacrylate Copolymers Grafted ontoPolybutadiene Seeds [R] . Aerdts, A. M. 1993

机译：聚苯乙烯接枝苯乙烯甲基丙烯酸甲酯共聚物的微观结构

Free radical copolymerization of tert-butyl 3-isopropenylcumylperoxide with styrene and grafting of methyl methacrylate onto the copolymers

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