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Proton-conductive membranes of sulfonated polyphenylsulfone

机译:磺化聚苯砜的质子传导膜

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摘要

Polyphenylsulfone was sulfonated by two different methods: reaction with SO3 and reaction with (CH3)(3)SiSO3Cl. The products were characterized, and the advantages of both methods are discussed. Much more homogeneous products were obtained from the reaction with (CH3)(3)SiSO3Cl, along with better control of the sulfonation degree. An alternative method of membrane preparation led to an asymmetric structure, which allowed the combination of high mechanical stability and high proton conductance. (C) 2002 Wiley Periodicals, Inc. [References: 18]
机译:聚苯砜通过两种不同的方法磺化:与SO3反应和与(CH3)(3)SiSO3Cl反应。对产品进行了表征,并讨论了两种方法的优点。与(CH3)(3)SiSO3Cl的反应获得了更多的均相产物,并且更好地控制了磺化度。另一种膜制备方法导致结构不对称,从而实现了高机械稳定性和高质子传导性的结合。 (C)2002 Wiley Periodicals,Inc. [参考:18]

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