• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Journal of Applied Polymer Science >SYNTHESIS AND FLAME-RETARDANT PROPERTIES OF PHOSPHORUS-CONTAINING POLYMERS BASED ON POLY(4-HYDROXYSTYRENE)
【24h】

SYNTHESIS AND FLAME-RETARDANT PROPERTIES OF PHOSPHORUS-CONTAINING POLYMERS BASED ON POLY(4-HYDROXYSTYRENE)

机译：基于聚（4-羟基苯乙烯）的含磷聚合物的合成及阻燃性能

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Phosphorus-containing polystyrene was obtained through incorporating phosphate groups onto poly(4-hydroxystyrene). This was achieved by esterification with diethylchlorophosphate. The phosphorylation was confirmed by IR, H-1-NMR, and P-31-NMR analysis. By varying the feeding ratios of the reactants, the phosphorus content in the polymers could be successfully tailored and gave values of 12.8 to 4.9% by weight. This was further corroborated by elemental analysis. Thermal characteristics and temporal stability of the phosphorylated polymers were evaluated by DSC and TGA. High char yields (64% by weight) and LOI values of 41 were found for these polymers. Such properties make these polymers useful in flame retardants. (C) 1996 John Wiley & Sons, Inc. [References: 17]
机译：通过将磷酸基团结合到聚（4-羟基苯乙烯）上获得含磷的聚苯乙烯。这是通过用二乙基氯磷酸酯化来实现的。通过IR，H-1-NMR和P-31-NMR分析确认磷酸化。通过改变反应物的进料比，可以成功地调整聚合物中的磷含量，其值为12.8至4.9重量％。元素分析进一步证实了这一点。通过DSC和TGA评估磷酸化聚合物的热特性和时间稳定性。对于这些聚合物，发现高的炭收率（64重量％）和LOI值为41。这些特性使这些聚合物可用于阻燃剂。 （C）1996 John Wiley＆Sons，Inc. [参考：17]

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号