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EFFECT OF THE MIXING CONDITIONS ON THE PHASE STRUCTURE OF PP/PS BLENDS

机译:混合条件对PP / PS共混物相结构的影响

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摘要

The effect of the rate and time of mixing in a batch mixer on the phase structure of polypropylene/polystyrene (PP/PS) blends with various theological properties of the components was studied. Regions with substantially different average sizes of the dispersed particles were found in the studied blends. Differences between the average size of the particles in individual regions of the samples persist in all blends and mixing conditions under study. No dependence of the average particle size on the rate of mixing has been obtained for the PP/PS (75/25) blends. On the other hand, decrease of the average particle size with increasing rate of mixing has been found for the PP/PS (95/5) blend. These results are discussed as a consequence of the competition between the breakup and coalescence of the dispersed particles. (C) 1996 John Wiley & Sons, Inc. [References: 32]
机译:研究了分批混合机中混合速率和时间对具有各种流变特性的聚丙烯/聚苯乙烯(PP / PS)共混物相结构的影响。在所研究的共混物中发现了分散颗粒的平均尺寸明显不同的区域。在所研究的所有混合和混合条件下,样品各个区域中颗粒平均尺寸之间的差异仍然存在。对于PP / PS(75/25)共混物,没有获得平均粒度对混合速率的依赖。另一方面,对于PP / PS(95/5)共混物,发现平均粒度随混合速率的增加而降低。由于分散颗粒的破裂和聚结之间存在竞争,因此对这些结果进行了讨论。 (C)1996 John Wiley&Sons,Inc. [参考:32]

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