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Use of crosslinked poly(ferric acrylate) as a sorbent in solid-phase extraction

机译:交联聚丙烯酸铁在固相萃取中作为吸附剂的用途

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A sample-preparation step, before chromatographic analysis, is frequently performed to enrich the components of interest from a complex matrix. This step is also needed to purify and concentrate the analyte present in a highly dilute medium. Solid-phase extraction (SPE) with a specific sorbent is one of the most widely used techniques for extracting trace components from aqueous or nonaqueous media. In this method, analytes are extracted by the passage of the medium through a cartridge containing a solid matrix. The recovery of the analytes from the medium considerably depends on the extent of the interactions between the analytes and the sorbent. Through the enhancement of these interactions, the extent of the uptake of the analytes can be improved. Poly(acrylic acid) is commonly employed as the sorbent in SPE for the isolation of polar analytes. This article discusses the use of the metal-containing polymer poly(ferric acrylate) as the sorbent for the isolation of a few phenols as representative components from water. The results indicate that the metal-containing polymer has an enhanced adsorption capacity in comparison with the capacity of the widely used sorbent poly(acrylic acid). (C) 2002 John Wiley Sons, Inc. [References: 5]
机译:在色谱分析之前,通常需要执行样品制备步骤,以从复杂的基质中富集目标组分。还需要此步骤来纯化和浓缩存在于高度稀释的介质中的分析物。具有特定吸附剂的固相萃取(SPE)是从水性或非水性介质中萃取痕量组分的最广泛使用的技术之一。在这种方法中,通过使介质通过包含固体基质的试剂盒,可以提取分析物。从介质中分析物的回收率在很大程度上取决于分析物与吸附剂之间相互作用的程度。通过增强这些相互作用,可以提高分析物的吸收程度。聚丙烯酸通常用作SPE中的吸附剂,用于分离极性分析物。本文讨论了使用含金属的聚合物聚(丙烯酸铁)作为吸附剂从水中分离出几种酚作为代表成分的方法。结果表明,与广泛使用的吸附剂聚丙烯酸相比,含金属的聚合物具有增强的吸附能力。 (C)2002 John Wiley Sons,Inc. [参考:5]

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