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Resin-vulcanized NBR: Suitability of rheometric parameters for the calculation of cure kinetic constants

机译:树脂硫化的NBR:流变参数对固化动力学常数计算的适用性

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摘要

Several mechanisms can be used to describe the vulcanization process, and study of the reactions that actually take place can be done through different techniques. In this work, two methods that used rheometric parameters to calculate the kinetic constant were compared for the cure of nitrile rubber with a system of phenolic resin, polychloroprene, and zinc oxide. The formulations and data analysis were based on a complete factorial experiment design. The results enabled the identification of the influence of each parameter involved in the vulcanization process and the suitability of the two methods used. (C) 2002 John Wiley Sons, Inc. [References: 8]
机译:可以使用几种机制来描述硫化过程,并且可以通过不同的技术来研究实际发生的反应。在这项工作中,使用酚醛树脂,聚氯丁二烯和氧化锌体系比较了使用流变参数计算动力学常数的两种方法,用于丁腈橡胶的硫化。配方和数据分析基于完整的析因实验设计。结果使得能够确定硫化过程中涉及的每个参数的影响以及所使用的两种方法的适用性。 (C)2002 John Wiley Sons,Inc. [参考:8]

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